STRUCTURE OF BIS(4-METHYLPYRIDINE-N)COPPER(I) BROMIDE

被引：5

作者：

JEDRZEJAS, MJ

MARTUCH, RA

TOWNS, RLR

BAKER, RJ

DURAJ, SA

HEPP, AF

机构：

[1] CLEVELAND STATE UNIV,DEPT CHEM,CLEVELAND,OH 44115

[2] NASA,LEWIS RES CTR,PHOTOVOLTAIC BRANCH,CLEVELAND,OH 44135

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷 / 03期

关键词：

D O I：

10.1107/S0108270192006279

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bromobis(4-methylpyridine)copper(I), [CuBr(C6H7N)2], M(r) = 329.71, triclinic, P1BAR, a = 9.254 (7), b = 9.736 (3), c = 7.955 (3) angstrom, alpha = 102.34 (3), beta = 112.33 (3), gamma = 95.09 (4)-degrees, V = 636.2 (6) angstrom3 , Z = 2, D(m) = 1.8, D(x) = 1.721 g cm-3, lambda(Mo Kalpha) = 0.710326 angstrom, mu = 50.84 cm-1, F(000) = 328, T = 293 K, R = 0.057, wR = 0.088, for 1517 independent observed [I > 3sigma(I)] reflections. An interesting structural feature of this compound is a distance between Cu atoms of 3.101 (2) angstrom within the same unit cell compared to a distance of 6.124 (2) angstrom between Cu atoms of different unit cells.

引用

页码：536 / 538

页数：3

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