ENANTIOMERICALLY PURE GUANIDINE-CATALYZED ASYMMETRIC NITROALDOL REACTION

被引：186

作者：

CHINCHILLA, R ^{[1
]}

NAJERA, C ^{[1
]}

SANCHEZAGULLO, P ^{[1
]}

机构：

[1] UNIV ALICANTE,FAC CIENCIAS,DEPT QUIM ORGAN,E-03080 ALACANT,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 07期

关键词：

D O I：

10.1016/0957-4166(94)80183-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically pure guanidines with and without C-2 symmetry have been prepared and used as catalysts in the addition of nitromethane to aldehydes (Henry reaction). The influence of the structure and amount of the guanidine, the solvent and the temperature in the enantioselectivity of the nitroaldol reaction has also been studied.

引用

页码：1393 / 1402

页数：10

共 50 条

[31] Trends in lipase-catalyzed asymmetric access to enantiomerically pure/enriched compounds
Ghanem, Ashraf
TETRAHEDRON, 2007, 63 (08) : 1721 - 1754
[32] Synthesis of enantiomerically pure tributylstannylcyclopropanes through lipase-catalyzed reaction
Itoh, T
Emoto, S
Kondo, M
TETRAHEDRON, 1998, 54 (20) : 5225 - 5232
[33] Synthesis of enantiomerically pure tributylstannylcyclopropanes through lipase-catalyzed reaction
Itoh, T.
Emoto, S.
Kondo, M.
Tetrahedron, 54 (20):
[34] Bicyclic guanidine-catalyzed enantioselective phospha-Michael reaction:: synthesis of chiral β-aminophosphine oxides and β-aminophosphines
Fu, Xiao
Jiang, Zhiyong
Tan, Choon-Hong
CHEMICAL COMMUNICATIONS, 2007, (47) : 5058 - 5060
[35] Chiral Bifunctional Guanidine-Catalyzed Enantioselective Aza-Henry Reaction of Isatin-Derived Ketimines
Fang, Bing
Liu, Xiaohua
Zhao, Jiannan
Tang, Yu
Lin, Lili
Feng, Xiaoming
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (06): : 3332 - 3338
[36] Access to the nicotine system by application of a guanidine-catalyzed asymmetric Michael addition of diphenyliminoacetate with 3-pyridyl vinyl ketone
Zhang, Gang
Kumamoto, Takuya
Heima, Takashi
Ishikawa, Tsutomu
TETRAHEDRON LETTERS, 2010, 51 (30) : 3927 - 3930
[37] ENANTIOMERICALLY PURE COMPOUND SYNTHESIS BY ASYMMETRIC GLYOXYLATE ENE REACTION WITH VINYLIC SULFIDES AND SELENIDES CATALYZED BY A CHIRAL TITANIUM COMPLEX
TERADA, M
MATSUKAWA, S
MIKAMI, K
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) : 327 - 328
[38] Asymmetric reduction of an enantiomerically pure γ-polyketone
Nozaki, M
Kosaka, N
Muguruma, S
Hiyama, T
MACROMOLECULES, 2000, 33 (15) : 5340 - 5346
[39] Potassium phosphate catalyzed nitroaldol reaction
Desai, UV
Pore, DM
Mane, RB
Solabannavar, SB
Wadgaonkar, PP
SYNTHETIC COMMUNICATIONS, 2004, 34 (01) : 19 - 24
[40] Guanidine-catalyzed asymmetric synthesis of 2,2-disubstituted chromane skeletons by intramolecular oxa-Michael addition
Saito, Noriko
Ryoda, Akemi
Nakanishi, Waka
Kumamoto, Takuya
Ishikawa, Tsutomu
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (16) : 2759 - 2766

← 1 2 3 4 5 →