NON-STEADY-STATE MODEL FOR KINETICS OF FREE-RADICAL POLYMERIZATION .2. REDOX INITIATION

被引：2
|
作者：
YAN, DY [1 ]
LIN, JM [1 ]
YUAN, CM [1 ]
FENG, J [1 ]
机构：
[1] SHANGHAI JIAO TONG UNIV,DEPT APPL CHEM,SHANGHAI 200030,PEOPLES R CHINA
来源：
POLYMER INTERNATIONAL | 1992年 / 28卷 / 02期
关键词：
RADICAL POLYMERIZATION; REDOX INITIATION; KINETICS OF POLYMERIZATION; NON-STEADY-STATE MODEL; MOLECULAR WEIGHT DISTRIBUTION; MOLECULAR PARAMETERS;
D O I：
10.1002/pi.4990280204
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This work deals with the non-steady-state kinetics of free radical polymerization with redox initiation. Rigorous expressions for the radical concentration, monomer conversion, molecular size distribution function, and number-average and weight-average molecular weights, etc., were derived. The molecular parameters of the resulting polymer were evaluated in relation to the polymerization conditions.
引用
收藏
页码：115 / 121
页数：7
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