SYNTHESIS, CHARACTERIZATION AND LUMINESCENCE PROPERTIES OF LANTHANIDE(III) COMPLEXES WITH 2,6-BIS(BENZIMIDAZOL-2'-YL)PYRIDINE

被引：33
|
作者：
WANG, SX
LUO, QH
ZHOU, XX
ZENG, ZZ
机构：
[1] NANJING UNIV,INST COORDINAT CHEM,NANJING 210008,PEOPLES R CHINA
[2] LANZHOU UNIV,DEPT CHEM,LANZHOU 730000,PEOPLES R CHINA
来源：
POLYHEDRON | 1993年 / 12卷 / 15期
关键词：
D O I：
10.1016/S0277-5387(00)81434-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New complexes of hydrated lanthanide(III) nitrates with 2,6-bis(benzimidazol-2'-yl)pyridine (BBP) having the formulae [Ln(BBP)2(NO3)2]NO3 . nH2O (where Ln = La-Nd, Sm-Tb, n = 1, 2), [Ln(BBP)(BBP-H)(NO3)(OH2)]NO3 . nH2O (where Ln = Dy, Er, n = 3,4) and (Ln(BBP-H)(NO3)2(OH2)] . 2H2O (where Ln = Lu) have been prepared and characterized by elemental analyses, IR and electronic spectra, molar conductance, thermal analyses and X-ray powder diffraction patterns. The emission spectra of all the complexes have also been examined. It has been found that all the complexes show the luminescence of the ligand. The Sm, Eu and Tb complexes also show the corresponding metal ion luminescence.
引用
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页码：1939 / 1945
页数：7
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