ELECTRONIC-PROPERTIES OF ISOSTRUCTURAL ORGANIC CONDUCTORS (ET)(3)(HSO4)(2) AND [NI(DDDT)(2)](3)(HSO4)(2) - THERMOPOWER AND TIGHT-BINDING CALCULATIONS

被引：7
|
作者：
MERZHANOV, VA [1 ]
HITS, DA [1 ]
YAGUBSKII, EB [1 ]
DOUBLET, ML [1 ]
CANADELL, E [1 ]
机构：
[1] UNIV PARIS 11,CHIM THEOR LAB,F-91405 ORSAY,FRANCE
来源：
SYNTHETIC METALS | 1995年 / 71卷 / 1-3期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1016/0379-6779(94)03083-I
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The temperature dependence of thermopower of isostructural molecular conductors [Ni(dddt)(2)](3)(HSO4)(2) and (ET)(3)(HSO4)(2) has been investigated. Drastic difference in S(T) dependences is qualitatively explained on basis of tight binding band structure calculations. A peak at 25 K in [Ni(dddt)(2)](3)(HSO4)(2) was shown to be manifestation of metal to semimetal phase transition, and the abrupt decrease at 125 K in (ET)(3)(HSO4)(2) is concerned with metal to insulator phase transition. Rather complex semimetal band structure was found in both cases.
引用
收藏
页码：1867 / 1868
页数：2
相关论文
共 50 条
  • [21] SUPERPROTONIC CONDUCTIVITY IN CS-3(HSO4)(2)(H2PO4)
    HAILE, SM
    LENTZ, G
    KREUER, KD
    MAIER, J
    SOLID STATE IONICS, 1995, 77 : 128 - 134
  • [22] THE STRUCTURE OF Cs5(HSO4)3(H2PO4)2
    Staneff, G.
    Calkins, P.
    Fu, S.
    Haile, S. M.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C438 - C438
  • [23] Solvent effects in the oxidation of sulfides with NaBrO3/Mg(HSO4)2
    Shaabani, A
    Bazgir, A
    Soleimani, K
    Salehi, P
    SYNTHETIC COMMUNICATIONS, 2003, 33 (17) : 2935 - 2944
  • [24] Charge ordering state of β"-(ET)3(HSO4)2 and β"-(ET)3(ClO4)2 by temperature-dependent infrared and Raman spectroscopy
    Yamamoto, T
    Uruichi, M
    Yakushi, K
    Kawamoto, A
    PHYSICAL REVIEW B, 2006, 73 (12)
  • [25] K3[Pt2(SO4)4H(HSO4)2]:: A platinum(III) sulfate with [Pt2(SO4)4] cores linked by [H(HSO4)2]- units
    Pley, M
    Wickleder, MS
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (2-3): : 592 - 595
  • [26] CRYSTAL-STRUCTURE OF SR(HSO4)2=SR[SO3(OH)]2
    SIMONOV, MA
    TROYANOV, SI
    KEMNITZ, E
    HASS, D
    KAMMLER, M
    KRISTALLOGRAFIYA, 1988, 33 (01): : 245 - 246
  • [27] Structure of Cs4(HSO4)3(H2PO4) single crystals
    I. P. Makarova
    V. V. Grebenev
    I. I. Vasil’ev
    E. V. Dmitricheva
    V. A. Komornikov
    V. V. Dolbinina
    A. S. Mikheikin
    Crystallography Reports, 2016, 61 : 18 - 23
  • [28] Structure of Cs4(HSO4)3(H2PO4) single crystals
    Makarova, I. P.
    Grebenev, V. V.
    Vasil'ev, I. I.
    Dmitricheva, E. V.
    Komornikov, V. A.
    Dolbinina, V. V.
    Mikheikin, A. S.
    CRYSTALLOGRAPHY REPORTS, 2016, 61 (01) : 18 - 23
  • [29] Phase transitions in Cs5(HSO4)2(H2PO4)3 crystal
    V. V. Grebenev
    I. P. Makarova
    D. A. Ksenofontov
    V. A. Komornikov
    E. V. Dmitricheva
    Crystallography Reports, 2013, 58 : 894 - 898
  • [30] Investigation of the structure of Cs3(HSO4)2(H2PO4) single crystals
    I. P. Makarova
    V. V. Grebenev
    I. I. Vasiliev
    E. V. Dmitricheva
    V. A. Komornikov
    V. V. Dolbinina
    Crystallography Reports, 2015, 60 : 498 - 507
12345