THE ADSORPTION SITE OF AMMONIA AT COPPER SURFACES

被引：4
|
作者：
BIEMOLT, W
DAVIES, PR
JANSEN, APJ
VANSANTEN, RA
机构：
[1] UNIV WALES COLL CARDIFF,COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES
[2] EINDHOVEN UNIV TECHNOL,INORGAN CHEM & CATALYSIS LAB,5600 MB EINDHOVEN,NETHERLANDS
来源：
CATALYSIS TODAY | 1992年 / 12卷 / 04期
关键词：
D O I：
10.1016/0920-5861(92)80059-V
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The adsorption of ammonia at copper surfaces was studied using Hartree-Fock-Slater LCAO calculations to investigate ammonia interaction with copper clusters. Important factors influencing ammonia adsorption were established from trends in its behaviour at clusters of different size. Adsorption at different coordination sites was examined in light of these results and it was found that a strong electrostatic contribution directs the ammonia towards lower coordination sites.
引用
收藏
页码：427 / 432
页数：6
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