DYNAMICS AND STRUCTURE DEVELOPMENT DURING HIGH-SPEED MELT SPINNING OF NYLON-6 .1. ONLINE EXPERIMENTAL MEASUREMENTS

被引:18
|
作者
BHEDA, JH
SPRUIELL, JE
机构
[1] UNIV TENNESSEE,DEPT MAT SCI & ENGN,KNOXVILLE,TN 37996
[2] UNIV TENNESSEE,CTR MAT PROC,KNOXVILLE,TN 37996
关键词
D O I
10.1002/app.1990.070390219
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
On‐line experimental measurements of filament diameter, temperature, and birefringence as a function of distance from the spinneret were carried out during melt spinning of two nylon 6 resins of differing molecular weight. Filament tension was also measured. A rapid diameter attenuation or “necking” was observed in the spinline for both resins at take‐up velocities above 6000 m/min. Evidence of crystallization in the spinline was also observed at these high spinning speeds. An analytical technique was used to extract apparent elongational viscosity for each resin and heat transfer coefficient for the melt spinning process from the experimental results. Copyright © 1990 John Wiley & Sons, Inc.
引用
收藏
页码:447 / 463
页数:17
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