SYNTHESIS OF OPTICALLY-ACTIVE GAMMA-LACTONES AND DOPANTS FOR FERROELECTRIC LIQUID-CRYSTALS POSSESSING A TRIFLUOROMETHYL GROUP

被引:14
|
作者
WATANABE, S
SAKAI, Y
TAKEDA, M
KITAZUME, T
YAMAZAKI, T
机构
[1] KASHIMA OIL CO LTD,DEPT RES & DEV,KAMISUMACHI,IBARAKI 31402,JAPAN
[2] TOKYO INST TECHNOL,DEPT BIOENGN,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN
关键词
D O I
10.1016/0022-1139(93)02948-E
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of trans- and cis-gamma-lactones with high optical purity have been prepared from the lactonization of (S)-(-)-2-(trifluoromethyl)-4-pentenoic acid (>94% ee) under acidic conditions. These materials have been transformed into new types of dopant for ferroelectric liquid crystals possessing a trifluoromethyl group.
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页码:149 / 152
页数:4
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