POLAROGRAPHIC-DETERMINATION OF CARBODIIMIDES

被引：1
|
作者：
HALADJIAN, J
BIANCO, P
机构：
[1] Laboratoire de Chimie et Electrochimie des Complexes, Laboratoire de Chimie Bactérienne, CNRS, 13331 Marseille Cedex 3, Case 57, Place Victor-Hugo
来源：
ANALYTICA CHIMICA ACTA | 1990年 / 234卷 / 02期
关键词：
Carbodiimides;
D O I：
10.1016/S0003-2670(00)83593-X
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
N′-Cyclohexyl-N-(2-morpholinoethyl)carbodiimide metho-p-toluenesulphonate (CMCT) is irreversibly reduced via a two-electron mechanism at a mercury electrode. A differential-pulse polarographic study of this reduction led to a method for determining CMCT. From a study of CMCT hydrolysis at different pH values, the second-order rate constant of this reaction was determined at 25°C. © 1990.
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页码：471 / 473
页数：3
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