RUTHENIUM CARBONYL 1,4-DIAZA-1,3-BUTADIENE (R-DAB) COMPLEXES .5. SYNTHESES, SPECTROSCOPIC PROPERTIES, AND REACTIVITY OF RU2(CO)5(ALKYL-DAB), A KEY INTERMEDIATE IN THE RU3(CO)12-ALKYL-DAB REACTION - CRYSTAL AND MOLECULAR-STRUCTURE OF (1,4-DIISOPROPYL-1,4-DIAZA-1,3-BUTADIENE)PENTACARBONYLDIRUTHENIUM, RU2(CO)5(I-PR-DAB)IN

被引：50

作者：

KEIJSPER, J

POLM, L

VANKOTEN, G

VRIEZE, K

ABBEL, G

STAM, GH

机构：

[1] UNIV AMSTERDAM,ANORGAN CHEM LAB,1018 WV AMSTERDAM,NETHERLANDS

[2] UNIV AMSTERDAM,KRISTALLOG LAB,1018 WV AMSTERDAM,NETHERLANDS

来源：

INORGANIC CHEMISTRY | 1984年 / 23卷 / 14期

关键词：

D O I：

10.1021/ic00182a031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2142 / 2148

页数：7

共 41 条

[21] Bonding properties of a novel inorganometallic complex, Ru(SnPh(3))(2)(CO)(2)(iPr-DAB) (iPr-DAB=N,N'-diisopropyl-1,4-diaza-1,3-butadiene), and its stable radical-anion, studied by UV-Vis, IR, and EPR spectroscopy, (spectro-) electrochemistry, and density functional calculations
Aarnts, MP
Wilms, MP
Peelen, K
Fraanje, J
Goubitz, K
Hartl, F
Stufkens, DJ
Baerends, EJ
Vlcek, A
INORGANIC CHEMISTRY, 1996, 35 (19) : 5468 - 5477
[22] A combined spectroscopic, photophysical and theoretical (DFT) study of the electronically excited inorganometallic complexes [Ru(E)(E')(CO)(2)(iPr-DAB)] (E=Cl, Me, SnPh(3), PbPh(3); E'=GePh(3), SnR(3), PbR(3) (R=Me, Ph); iPr-DAB=N,N'-diisopropyl-1,4-diaza-1,3-butadiene): Evidence of an exceptionally long-lived (3)sigma pi* excited state for [Ru(SnPh(3))(2)(CO)(2)(iPr-DAB)]
Aarnts, MP
Stufkens, DJ
Wilms, MP
Baerends, EJ
Vlcek, A
Clark, IP
George, MW
Turner, JJ
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (12) : 1556 - 1565
[23] Temperature-dependent photophysical, photochemical and redox properties of novel complexes (CO)2CpRu-Ru(Ln)-RuCp(CO)2 and (CO)2CpRu-Ru(Ln)-SnPh3 [Ln = (CO)2(N,N′-diisopropyl-1,4-diaza-1,3-butadiene)]
van Slageren, J
Hartl, F
Stufkens, DJ
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2000, (05) : 847 - 855
[24] Spectroelectrochemical (UV-Vis, IR, NMR, and EPR) study of the inorganometallic complexes Ru(E)(E')(CO)(2)(iPr-DAB) (E = Cl, E' = SnPh3, PbPh3; E = Me, SnPh3, GePh3, E' = SnPh3; E = E' = PbPh3; iPr-DAB = 1,4-diisopropyl-1,4-diaza-1,3-butadiene)
Aarnts, MP
Hartl, F
Peelen, K
Stufkens, DJ
Amatore, C
Verpeaux, JN
ORGANOMETALLICS, 1997, 16 (21) : 4686 - 4695
[25] MIXED ALKYL ISOCYANIDE-1,4-DIAZA-1,3-BUTADIENE COMPLEXES OF CHROMIUM - A SERIES OF 17-ELECTRON, 18-ELECTRON AND 19-ELECTRON SPECIES OF THE TYPE [(CR(CO)3(CNR)(R'-DAB)]1+,0,1-
BELL, A
WALTON, RA
POLYHEDRON, 1986, 5 (04) : 951 - 958
[26] MIXED ALKYL ISOCYANIDE-1,4-DIAZA-1,3-BUTADIENE COMPLEXES OF CHROMIUM .2. SECONDARY-ION, ELECTRON-IMPACT AND CHEMICAL-IONIZATION MASS-SPECTROMETRY OF THE 18-ELECTRON SPECIES CR(CO)3(CNR)(R'-DAB)
DETTER, LD
WALTON, RA
POLYHEDRON, 1986, 5 (08) : 1321 - 1328
[27] Variation in charge-transfer photochemistry clarified by a CASSCF/MR-CCI comparative study of the low-lying excited states of M(R)(CO)3(H-DAB) (M = Mn, R = H, methyl, ethyl, M = Re, R = H, DAB = 1,4-diaza-1,3-butadiene)
Guillaumont, D
Wilms, MP
Daniel, C
Stufkens, DJ
INORGANIC CHEMISTRY, 1998, 37 (22) : 5816 - 5822
[28] SYNTHESIS AND CHARACTERIZATION OF 2 ISOMERS OF DECACARBONYL(1,4-DIALKYL-1,4-DIAZA-1,3-BUTADIENE)TRIOSMIUM - OS3(CO)10(R-DAB) .1. FLUXIONAL BEHAVIOR OF OS3(CO)10(I-PR-DAB(4E)) - MOLECULAR-STRUCTURES OF THE 48E CLUSTER OS3(CO)10(I-PR-DAB(4E)) AND OF THE 50E CLUSTER OS3(CO)10(C-PR-DAB(6E)) CONTAINING A 4E DONOR SIGMA,SIGMA-N,N' AND A 6E DONOR SIGMA-N, MU-2-N', NETA-2-C=N' BONDED R-DAB LIGAND, RESPECTIVELYB
ZOET, R
JASTRZEBSKI, JTBH
VANKOTEN, G
MAHABIERSING, T
VRIEZE, K
HEIJDENRIJK, D
STAM, CH
ORGANOMETALLICS, 1988, 7 (10) : 2108 - 2117
[29] Electrochemical and IR/UV-vis spectroelectrochemical studies of fac-[Mn(X)(CO)(3)(iPr-DAB)](n) (n = 0, X = Br, Me, Bz; n = +1, X = THF, MeCN, nPrCN, P(OMe)(3); iPr-DAB = 1,4-diisopropyl-1,4-diaza-1,3-butadiene) at variable temperatures: Relation between electrochemical and photochemical generation of [Mn(CO)(3)(alpha-diimine)](-)
Rossenaar, BD
Hartl, F
Stufkens, DJ
Amatore, C
Maisonhaute, E
Verpeaux, JN
ORGANOMETALLICS, 1997, 16 (21) : 4675 - 4685
[30] UV-visible absorption spectra of [Ru(E)(E′)(CO)2(iPr-DAB)] (E = E′ = SnPh3 or Cl; E = SnPh3 or Cl, E′ = CH3; iPr-DAB = N,N′-di-isopropyl-1,4-diaza-1,3-butadiene):: Combination of CASSCF/CASPT2 and TD-DFT calculations
Turki, M
Daniel, C
Zális, S
Vlcek, A
van Slageren, J
Stufkens, DJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (46) : 11431 - 11440

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