STUDY OF CHEMICAL-EQUILIBRIA IN METHANOL SYNTHESIS .1. EXPERIMENTAL-MEASUREMENT OF CHEMICAL-EQUILIBRIUM COMPOSITION AND CONSTANT KP

被引：0
|
作者：
LIU, H [1 ]
LUO, ZC [1 ]
ZHU, BC [1 ]
机构：
[1] E CHINA UNIV SCI & TECHNOL,DEPT CHEM ENGN,SHANGHAI 200287,PEOPLES R CHINA
来源：
FUEL SCIENCE & TECHNOLOGY INTERNATIONAL | 1994年 / 12卷 / 06期
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D O I：
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中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The chemical equilibrium compositions and equilibrium constants of methanol synthesis reactions, starting from carbon monoxide, carbon dioxide and hydrogen, were studied experimentally at P=4.0-6.6MPa and t=220 approximately 260-degrees-C. It was found that lower temperatures and higher pressures are favourable to chemical equilibria in the interested range of the synthesis reactions using low-pressure process, but the influence of temperature on K(P) is much larger than that of pressure.
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页码：815 / 827
页数：13
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