KINETICS OF THE LIQUID-PHASE SYNTHESIS AND HYDROLYSIS OF BUTYL LACTATE CATALYZED BY CATION-EXCHANGE RESIN

被引:48
|
作者
DASSY, S
WIAME, H
THYRION, FC
机构
[1] Chemical Engineering Institute, Louvain University, Louvain-La-Nauve, B-1348, 1, Voie Minckelers
关键词
LACTIC ACID; ESTERIFICATION; KINETICS; CATION-EXCHANGE RESIN;
D O I
10.1002/jctb.280590206
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Esterification of lactic acid with butanol catalysed by cation-exchange resin was carried out in a batch reactor in dioxane and toluene. The reaction rate was found to be first order with respect to catalyst and acid concentrations. The inhibiting effect of water and butanol has been evaluated. The rate data were correlated with a kinetic model based on inhibition by water and butanol.
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页码:149 / 156
页数:8
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