KINETICS OF THE LIQUID-PHASE SYNTHESIS AND HYDROLYSIS OF BUTYL LACTATE CATALYZED BY CATION-EXCHANGE RESIN

被引：48
|
作者：
DASSY, S
WIAME, H
THYRION, FC
机构：
[1] Chemical Engineering Institute, Louvain University, Louvain-La-Nauve, B-1348, 1, Voie Minckelers
来源：
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 1994年 / 59卷 / 02期
关键词：
LACTIC ACID; ESTERIFICATION; KINETICS; CATION-EXCHANGE RESIN;
D O I：
10.1002/jctb.280590206
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
Esterification of lactic acid with butanol catalysed by cation-exchange resin was carried out in a batch reactor in dioxane and toluene. The reaction rate was found to be first order with respect to catalyst and acid concentrations. The inhibiting effect of water and butanol has been evaluated. The rate data were correlated with a kinetic model based on inhibition by water and butanol.
引用
收藏
页码：149 / 156
页数：8
相关论文
共 50 条
  • [1] KINETICS OF THE LIQUID-PHASE ESTERIFICATION OF ACRYLIC-ACID WITH BUTANOL CATALYZED BY CATION-EXCHANGE RESIN
    DARGE, O
    THYRION, FC
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1993, 58 (04) : 351 - 355
  • [2] Kinetic study for hydrolysis of methyl lactate catalyzed by cation-exchange resin
    Jiang, Shao-tong
    Liu, Mo
    Pan, Li-jun
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2010, 41 (02) : 190 - 194
  • [3] KINETICS OF THE HYDROLYSIS OF ETHYL-ACETATE CATALYZED BY CATION-EXCHANGE RESIN
    RAJAMANI, K
    SHENOY, SC
    RAO, MS
    RAO, MG
    JOURNAL OF APPLIED CHEMISTRY AND BIOTECHNOLOGY, 1978, 28 (11): : 699 - 708
  • [4] HYDROLYSIS OF DIETHYL SUCCINATE CATALYZED BY CATION-EXCHANGE RESIN
    GOTO, M
    GOTO, S
    TESHIMA, H
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (03) : 223 - 228
  • [5] KINETICS OF METHYL TERTIARY BUTYL ETHER LIQUID-PHASE SYNTHESIS CATALYZED BY ION-EXCHANGE RESIN .1. INTRINSIC RATE EXPRESSION IN LIQUID-PHASE ACTIVITIES
    REHFINGER, A
    HOFFMANN, U
    CHEMICAL ENGINEERING SCIENCE, 1990, 45 (06) : 1605 - 1617
  • [6] LIQUID-PHASE SYNTHESIS OF METHYL TERT-BUTYL ETHER CATALYZED BY ION-EXCHANGE RESIN
    SUBRAMANIAM, C
    BHATIA, S
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1987, 65 (04): : 613 - 620
  • [7] Kinetics of the hydrolysis of methyl acetate catalyzed by cation exchange resin
    Zhejiang Daxue Xuebao (Ziran Kexue Ban)/Journal of Zhejiang University (Natural Science Edition), 32 (04): : 411 - 418
  • [8] SYNTHESIS OF A NEW SULFONATED CATION-EXCHANGE RESIN AND ITS APPLICATION IN CATALYZED-HYDROLYSIS OF ESTERS
    METWALLY, MS
    ELHADI, MF
    ELWARDANY, MA
    RAZIK, AA
    JOURNAL OF MATERIALS SCIENCE, 1990, 25 (10) : 4223 - 4225
  • [9] KINETICS OF LIQUID-PHASE SYNTHESIS OF METHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND METHANOL CATALYZED BY ION-EXCHANGE RESIN
    MATOUQ, MH
    GOTO, S
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1993, 25 (10) : 825 - 831
  • [10] Liquid-phase esterification of methacrylic acid with methanol catalyzed by cation-exchange resin in a fixed bed reactor: Experimental and kinetic studies
    Liu, Junyang
    Wang, Luming
    Bian, Yuhang
    Li, Chunshan
    Li, Zengxi
    Li, Jie
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2023, 58 : 1 - 10
12345