REACTIVITY OF FUNCTIONALIZED DIPHOSPHIRANES AND 1,3-DIPHOSPHAPROPENES TOWARDS GRIGNARD-REAGENTS

被引：4

作者：

ELOUATIB, R ^{[1
]}

GAROT, C ^{[1
]}

ETEMADMOGHADAM, G ^{[1
]}

KOENIG, M ^{[1
]}

机构：

[1] UNIV TOULOUSE 3,SYNTH STRUCT & REACTIV MOLEC PHOSPHOREES LAB,CNRS,URA 454,F-31062 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 436卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)85044-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of saturated and unsaturated organomagnesium compounds with the monohalogenated diphosphiranes, 1a-b, and their isomers, the 1,3-diphosphapropenes, 2a-b, leads to a series of substituted 1,3-diphosphapropenes and 1,3-diphosphadienes 4-8 (a-b), but with the dihalogeno-derivatives 1c-d and 2c-d, it gives quantitative yields of 1,3-diphospha-allene 9. The reaction occurs via an anionic ring-opening involving an allylic anion intermediate 11a-b, detected by P-31 NMR.

引用

页码：169 / 177

页数：9

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