NH3 AND PH3 MOLECULAR QUADRUPOLE-MOMENTS AND THE SIGNS OF MOLECULAR G-VALUES

被引：3
|
作者：
COMBARIZA, J
SALZMAN, WR
KUKOLICH, SG
机构：
[1] Department of Chemistry, The University of Arizona, Tucson
来源：
CHEMICAL PHYSICS LETTERS | 1990年 / 167卷 / 06期
关键词：
D O I：
10.1016/0009-2614(90)85478-U
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Molecular Zeeman effect data for NH3 and PH3 was reviewed and reanalyzed to obtain molecular quadrupole moments. Since the signs of molecular g-values were not directly measured, molecular quadrupole moments were also calculated using ab initio SCF programs to remove ambiguities in the signs of g-values. For NH3, Qcc (measured) = -3.4(4) buckingham and Qcc (calculated) = -2.8 buckingham. For PH3, Qcc (measured) = -2.3(12) buckingham and Qcc (calculated) = -2.4 buckingham. These values support positive g-values for NH3 (gaa=gbb=0.568(2), gcc=0.500(2)), and for PH3 gaa=gbb=-0.325(9), and gcc=0.011(1). © 1990.
引用
收藏
页码：607 / 608
页数：2
相关论文
共 50 条
  • [31] Broadband Submillimeter Spectroscopy of HCN, NH3, and PH3 in the Troposphere of Jupiter
    Davis, G. R.
    Naylor, D. A.
    Griffin, M. J.
    Clark, T. A.
    Icarus International Journal of Solar System Studies, 130 (02):
  • [32] Influence of the curvature of the reaction path on tunneling in NH3, PH3 inversion
    Mamaev, VM
    Prisyazhnyuk, AV
    Berdyshev, DV
    Alekseiko, LN
    Babin, YV
    DOKLADY AKADEMII NAUK, 1997, 352 (02) : 211 - 213
  • [33] Broadband submillimeter spectroscopy of HCN, NH3, and PH3, in the troposphere of Jupiter
    Davis, GR
    Naylor, DA
    Griffin, MJ
    Clark, TA
    Holland, WS
    ICARUS, 1997, 130 (02) : 387 - 403
  • [34] MOLECULAR G VALUES, MAGNETIC SUSCEPTIBILITIES, MOLECULAR QUADRUPOLE MOMENT, AND SPIN-ROTATION INTERACTION IN 15NH3
    KUKOLICH, SG
    FLYGARE, WH
    MOLECULAR PHYSICS, 1969, 17 (02) : 127 - &
  • [35] MOLECULAR G-VALUES, MAGNETIC-SUSCEPTIBILITY ANISOTROPIES, MOLECULAR QUADRUPOLE-MOMENTS AND 2ND MOMENTS OF ELECTRON CHARGE-DISTRIBUTION IN ETHYLENE-OXIDE AND PYRIDINE ISOTOPES - ATTEMPT TO DETERMINE SIGN OF ELECTRIC-DIPOLE MOMENT
    HAMER, E
    SUTTER, DH
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1976, 31 (3-4): : 265 - 271
  • [36] FOCUSING MOLECULAR BEAMS OF NH3
    HELMER, JC
    JACOBUS, FB
    STURROCK, PA
    JOURNAL OF APPLIED PHYSICS, 1960, 31 (03) : 458 - 463
  • [37] MOLECULAR G-VALUES, MAGNETIC-SUSCEPTIBILITY ANISOTROPIES, MOLECULAR ELECTRIC QUADRUPOLE-MOMENTS, IMPROVED MOLECULAR ELECTRIC-DIPOLE MOMENTS AND N-14-QUADRUPOLE COUPLING-CONSTANTS OF ACRYLONITRILE, H2C=CH-CN, AND THE MAGNETIC-SUSCEPTIBILITY TENSOR OF THE NITRILE GROUP
    STOLZE, M
    SUTTER, DH
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1985, 40 (10): : 998 - 1010
  • [38] MOLECULAR ZEEMAN EFFECT IN NH3
    KUKOLICH, SG
    CASLETON, KH
    CHEMICAL PHYSICS LETTERS, 1973, 18 (03) : 408 - 410
  • [39] STRUCTURE AND ENERGETICS OF WEAKLY BOUND COMPLEXES - SYSTEMS INCORPORATING NH3 AND PH3
    SCHEINER, S
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1989, 59 : 117 - 129
  • [40] NH3 and PH3 line parameters:: the 2000 HITRAN update and new results
    Kleiner, I
    Tarrago, G
    Cottaz, C
    Sagui, L
    Brown, LR
    Poynter, RL
    Pickett, HM
    Chen, P
    Pearson, JC
    Sams, RL
    Blake, GA
    Matsuura, S
    Nemtchinov, V
    Varanasi, P
    Fusina, L
    Di Lonardo, G
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2003, 82 (1-4): : 293 - 312
12345