Synthesis and Characterization of Cerium(IV) Metallocenes

被引：14

作者：

Sutton, Andrew D. ^{[1
]}

Clark, David L. ^{[2
]}

Scott, Brian L. ^{[3
]}

Gordon, John C. ^{[1
]}

机构：

[1] Las Alamos Natl Lab, Chem Div Inorgan, Isotope & Actinide Chem C IIAC, Los Alamos, NM 87545 USA

[2] NSEC, Alamos Natl Lab, Los Alamos, NM 87545 USA

[3] Alamos Natl Lab, Mat Synth & Integrated Devices MPA 11, Los Alamos, NM 87545 USA

来源：

INORGANICS | 2015年 / 3卷 / 04期

关键词：

cerium; organometallic; cyclopentadiene; crystal structure;

D O I：

10.3390/inorganics3040589

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By applying a salt metathesis approach between Ce((OBu3)-Bu-t)(2)(NO3)(2)(THF)(2) and the potassium salts of mono-and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.

引用

页码：589 / 596

页数：8

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