Synthesis and Characterization of Cerium(IV) Metallocenes

被引：14
|
作者：
Sutton, Andrew D. [1 ]
Clark, David L. [2 ]
Scott, Brian L. [3 ]
Gordon, John C. [1 ]
机构：
[1] Las Alamos Natl Lab, Chem Div Inorgan, Isotope & Actinide Chem C IIAC, Los Alamos, NM 87545 USA
[2] NSEC, Alamos Natl Lab, Los Alamos, NM 87545 USA
[3] Alamos Natl Lab, Mat Synth & Integrated Devices MPA 11, Los Alamos, NM 87545 USA
来源：
INORGANICS | 2015年 / 3卷 / 04期
关键词：
cerium; organometallic; cyclopentadiene; crystal structure;
D O I：
10.3390/inorganics3040589
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By applying a salt metathesis approach between Ce((OBu3)-Bu-t)(2)(NO3)(2)(THF)(2) and the potassium salts of mono-and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.
引用
收藏
页码：589 / 596
页数：8
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