QUADRUPOLE ION TRAP MASS-SPECTROMETRY OF FULLERENES

被引：10
|
作者：
MORAND, KL
HOKE, SH
EBERLIN, MN
PAYNE, G
COOKS, RG
机构：
[1] Chemistry Department, Purdue University, West Lafayette, Indiana
[2] Universidade Estadual de Campinas, Campinas, Sao Paulo, 13081
来源：
ORGANIC MASS SPECTROMETRY | 1992年 / 27卷 / 03期
关键词：
D O I：
10.1002/oms.1210270321
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The fullereness C60 and C70 can be ionized by desorption from a liquid matrix upon bombardment by Cs+ ions of 7 keV kinetic energy. The resulting radical cations, when activated in the ion trap by collisions with Xe target, in the presence of helium, undergo extensive dissociation by loss of multiple C2 units. Large internal energies are deposited into these molecular ions and the dissociation efficiency is in excess of 60%.
引用
收藏
页码：284 / 288
页数：5
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