PHOTOABSORPTION SPECTRA OF CSNO AND CSN CLUSTERS

被引：22
|
作者：
FALLGREN, H
BROWN, KM
MARTIN, TP
机构：
[1] GOTHENBURG UNIV,S-41296 GOTHENBURG,SWEDEN
[2] MAX PLANCK INST FESTKORPERFORSCH,HEISENBERGSTR 1,W-7000 STUTTGART 80,GERMANY
来源：
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS | 1991年 / 19卷 / 1-4期
关键词：
D O I：
10.1007/BF01448260
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
Photoabsorption spectra of several CS(N + 2)O and Cs(N) clusters were obtained by means of laser-induced beam-depletion techniques. The strong absorption of clusters with N greater-than-or-equal-to 3 in the near infrared indicates that collective motion might play an important role. Dipole transitions between molecular orbitals, enhanced by plasmon oscillations, generate remarkably distinct spectra for (a) closed-shell clusters at N = 8 and (b) geometrically symmetric clusters like Cs6O and Cs14O.
引用
收藏
页码：81 / 84
页数：4
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