STEREOSELECTIVE SYNTHESIS OF BETA-AMINO HYDROXYLAMINES

被引：28

作者：

REETZ, MT ^{[1
]}

ROHRIG, D ^{[1
]}

HARMS, K ^{[1
]}

FRENKING, G ^{[1
]}

机构：

[1] UNIV MARBURG,FACHBEREICH CHEM,D-35043 MARBURG,GERMANY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 47期

关键词：

D O I：

10.1016/S0040-4039(00)78492-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral gamma-N,N-dibenzylamino-substituted alpha,beta-unsaturated carboxylic acid esters and dicarboxylic acid esters, prepared in enantiomerically pure form from L-amino acids, under go diastereoselective Michael addition reactions with nitrogen nucleophiles of the type Me(3)SiNHOSiMe(3) and CH3NNOH; the products are novel beta-amino hydroxylamine derivatives having two defined stereogenic centers.

引用

页码：8765 / 8768

页数：4

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