LOW-TEMPERATURE OXIDATION OF CARBON-MONOXIDE BY OXYGEN CATALYZED WITH SUPPORTED CHLORIDE COMPLEXES OF PD(II) AND CU(II)

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作者
RAKITSKAYA, TL
PAINA, VY
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
It is established by potentiometric and kinetic techniques that at specific Pd(II):Cu(II):Cl- ratios, oxidation with oxygen takes place in a steady-state regime. It is shown that the catalysis is effected by Pd(II) and Cu(II) chloride complexes and not by their reduced forms. Supported and dissolved Pd(II)/Cu(II) catalysts for the oxidation of CO with analogous properties have been observed.
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页码:898 / 903
页数:6
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