INTRAMOLECULAR ELECTRON-TRANSFER ACROSS POLYENEBRIDGES

被引：3
|
作者：
THOMAS, JA
JONES, CJ
HAMOR, TA
MCCLEVERTY, JA
MABBS, F
COLLISON, D
HARDING, C
机构：
[1] UNIV BRISTOL,BRISTOL BS8 1TH,AVON,ENGLAND
[2] OPEN UNIV,MILTON KEYNES MK7 6AA,BUCKS,ENGLAND
[3] UNIV MANCHESTER,MANCHESTER M13 9PL,LANCS,ENGLAND
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1993年 / 234卷
关键词：
D O I：
10.1080/10587259308042903
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The new bipyridylpolyene bridged bimetallic complexes [{LMo(NO)Cl}NC5H5-(C2H2)n-C5H5N] (n = 2-4 all trans) have been synthesised along with their monometallic counterpart [{LMo(NO)Cl}NC5H5-(C2H2)n-C5H5N]. All of the bimetallic complexes exhibit EPR spectra consistent with fast electron exchange between the metal centres and may be reduced in two 1-electron processes, the separation between which decreases by approximately 166 mV per additional ethenyl unit.
引用
收藏
页码：103 / 108
页数：6
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