SYNTHESIS OF FUNCTIONALLY SUBSTITUTED POLYSILANES USING TRIFLUOROMETHANESULFONIC ACID

被引:42
|
作者
UHLIG, W [1 ]
机构
[1] MAX PLANCK INST COAL RES,W-4330 MULHEIM,GERMANY
关键词
D O I
10.1016/0022-328X(91)86257-Q
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The cleavage of silicon phenyl bonds in phenylmethylpolysilane by CF3SO3H leads to triflate derivatives of polysilanes. The polymers react with lithium derivatives or acidic element hydrogen compounds under formation of numerous substituted polysilanes.
引用
收藏
页码:C45 / C49
页数:5
相关论文
共 50 条
  • [41] Synthesis and characterization of catalysts obtained by trifluoromethanesulfonic acid immobilization on zirconia
    Gorsd, Marina
    Blanco, Mirta
    Pizzio, Luis
    SCIENTIFIC BASES FOR THE PREPARATION OF HETEROGENEOUS CATALYSTS: PROCEEDINGS OF THE 10TH INTERNATIONAL SYMPOSIUM, 2010, 175 : 405 - 408
  • [42] Derivatization of steroids with dansylhydrazine using trifluoromethanesulfonic acid as catalyst
    Appelblad, P
    Ponten, E
    Jaegfeldt, LH
    Backstrom, T
    Irgum, K
    ANALYTICAL CHEMISTRY, 1997, 69 (23) : 4905 - 4911
  • [43] Oxidative coupling of lithium silenolates: First synthesis of bis(acyl)-substituted polysilanes
    Ohshita, J
    Masaoka, S
    Ishikawa, M
    ORGANOMETALLICS, 1996, 15 (09) : 2198 - 2200
  • [44] Electroluminescent Properties of Dialkyl Substituted Polysilanes
    Hoshino, Satoshi
    Suzuki, Hiroyuki
    Fujiki, Michiya
    Morita, Masao
    Matsumoto, Nobuo
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1998, 315 : 205 - 210
  • [45] Synthesis and some transformations of functionally substituted lactones
    Avetisyan, A. A.
    Alvandzhyan, A. G.
    Kostanyan, T. A.
    Bidar, M. M.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2011, 47 (06) : 910 - 913
  • [46] Synthesis of Functionally Substituted Cyano Carbonyl Compounds
    M. F. Pistsov
    O. M. Lavrova
    A. M. Saifutdinov
    R. N. Burangulova
    L. M. Kustov
    F. I. Guseinov
    R. Z. Musin
    Russian Journal of General Chemistry, 2017, 87 : 2887 - 2890
  • [47] Synthesis of Functionally Substituted Cyano Carbonyl Compounds
    Pistsov, M. F.
    Lavrova, O. M.
    Saifutdinov, A. M.
    Burangulova, R. N.
    Kustov, L. M.
    Guseinov, F. I.
    Musin, R. Z.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2017, 87 (12) : 2887 - 2890
  • [48] Synthesis of functionally substituted pyridine and thiophene derivatives
    Osman, AI
    El-Taweel, FMAA
    El-Awaad, SMH
    Elagamey, AGA
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1998, 37 (04): : 399 - 403
  • [49] Synthesis of functionally substituted isoxazole and isothiazole derivatives
    Potkin, V. I.
    Petkevich, S. K.
    Kletskov, A. V.
    Dikusar, E. A.
    Zubenko, Yu. S.
    Zhukovskaya, N. A.
    Kazbanov, V. V.
    Pashkevich, S. G.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 49 (10) : 1523 - 1533
  • [50] Synthesis of novel functionally substituted pyridazines and oxazines
    M. Hammouda
    Z. M. Abou Zeid
    M. A. Metwally
    Chemistry of Heterocyclic Compounds, 2008, 44 : 985 - 990