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INFLUENCE OF ETHOXYLATE DISTRIBUTION ON INTERFACIAL PROPERTIES OF LINEAR AND BRANCHED ETHOXYLATE SURFACTANTS
被引:9
|作者:
VARADARAJ, R
[1
]
BOCK, J
[1
]
GEISSLER, P
[1
]
ZUSHMA, S
[1
]
BRONS, N
[1
]
COLLETTI, T
[1
]
机构:
[1] EXXON CHEM CO,BATON ROUGE,LA 70821
关键词:
D O I:
10.1016/0021-9797(91)90172-5
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The influence of ethoxylate distribution on interfacial properties of linear and branched hydrophobe C12 and C13 alcohols is examined at the air-water, decane-water, and Teflon-water interfaces. In the polydisperse ethoxylates, the presence of unreacted alcohol and broad ethoxylate distribution causes interfacial properties to change significantly at the decane-water interface and moderately at the Teflon-water and air-water interfaces. The linear hydrophobe ethoxylate is more sensitive to the presence of unreacted alcohol and broad ethoxylate distribution than the branched hydrophobe ethoxylate. © 1991.
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页码:396 / 402
页数:7
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