STEREOCHEMISTRY AND DYNAMICS OF THE INCLUSION COMPLEX OF (S)-(+)-FENOPROFEN WITH CYCLOMALTOHEPTAOSE (BETA-CYCLODEXTRIN)

被引：23

作者：

UCCELLOBARRETTA, G ^{[1
]}

CHIAVACCI, C ^{[1
]}

BERTUCCI, C ^{[1
]}

SALVADORI, P ^{[1
]}

机构：

[1] CNR,DIPARTIMENTO CHIM & CHIM IND,CTR STUDIO MACROMOLEC STEREORDINATE & OTTICAMENTE ATT,I-56126 PISA,ITALY

来源：

CARBOHYDRATE RESEARCH | 1993年 / 243卷 / 01期

关键词：

D O I：

10.1016/0008-6215(93)84077-J

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The inclusion complex of the calcium salt of (S)-2-(3-phenoxyphenyl)propionic acid with cyclomaltoheptaose (beta-cyclodextrin) was investigated by H-1 NMR spectroscopy. The stoichiometry of the complex was determined by the continous variation method and the association constant by the Benesi-Hildebrand procedure. Measurements of proton selective relaxation rates allowed the dynamics of the complex to be investigated and the determination of intermolecular H-1{H-1}-NOE enhancements revealed the stereochemistry in solution.

引用

页码：1 / 10

页数：10

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