KINETICS AND MECHANISM OF HYDROGEN-PEROXIDE DECOMPOSITION BY HYDROXONITRILOTRI (METHYLENEPHOSPHONATO) MN(II)

被引：3
|
作者：
ANIS, SS
MANSOUR, MA
KHALIL, LH
机构：
来源：
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1991年 / 88卷 / 05期
关键词：
PEROXIDE; KINETICS; PHOSPHONATES; MANGANESE; COMPLEX;
D O I：
10.1051/jcp/1991880643
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The rate of reaction of Mn NTMP with H2O2 in KNO3 solution was investigated at various temperatures, and pH's. The general rate quation is [GRAPHICS] Values of k1 and K1 were calculated. The activation enthalpy (DELTA-H* = 84.0 KJ mol-1) and activation entropy (DELTA-S* = -6 JK-1 mol-1) were calculated from Arrhenius plots.
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页码：643 / 651
页数：9
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