TRAPPED-HOLE CENTERS IN IRRADIATED LI3VO4

被引：7
|
作者：
MURATA, T
MIKI, T
机构：
[1] Division of Materials Science and Engineering, Yamaguchi University, Ube, Yamaguchi 755
来源：
JOURNAL OF APPLIED PHYSICS | 1993年 / 73卷 / 03期
关键词：
D O I：
10.1063/1.353274
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Defects in lithium vanadate (Li3VO4) exposed to x rays were studied by electron spin resonance (ESR). 77 K irradiation produces two types of trapped-hole centers. One is supposed to be carbonate radical CO3-, which is thermally stable even at room temperature. Another, having a hyperfine interaction with a vanadium nucleus (I = 7/2, 99.76% natural abundant) is attributable to an intrinsic O- type center with one neighboring vanadium ion. The center is thermally unstable and anneals out around 200 K. In spite of the prominent detection of trapped-hole centers, ESR signals due to trapped-electron centers have not been clearly observed.
引用
收藏
页码：1110 / 1113
页数：4
相关论文
共 50 条
  • [31] Probing the capacity loss of Li3VO4 anode upon Li insertion and extraction
    Liao, Chaoyi
    Wen, Yanwei
    Shan, Bin
    Zhai, Tianyou
    Li, Huiqiao
    JOURNAL OF POWER SOURCES, 2017, 348 : 48 - 56
  • [32] Rapid hydrothermal synthesis of Li3VO4 with different favored facets
    Shi, Yi
    Zhang, Yi
    Liu, Lili
    Zhang, Zhijia
    Wang, Jun
    Chou, Shulei
    Gao, Jie
    Abruna, Hector D.
    Li, Huijun
    Liu, Huakun
    Wexler, David
    Wang, Jiazhao
    Wu, Yuping
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2017, 21 (09) : 2547 - 2553
  • [33] Approaching the Theoretical Capacity of Li3VO4 via Electrochemical Reconstruction
    Ni, Shibing
    Zhang, Jicheng
    Ma, Jianjun
    Yang, Xuelin
    Zhang, Lulu
    Li, Xiaoming
    Zeng, Haibo
    ADVANCED MATERIALS INTERFACES, 2016, 3 (01):
  • [34] Progress on Li3VO4 as a Promising Anode Material for Li-ion Batteries
    Mo, Jun
    Zhang, Xiumei
    Liu, Junjie
    Yu, Jingang
    Wang, Zhian
    Liu, Zaichun
    Yuan, Xinhai
    Zhou, Chunjiao
    Li, Ruilian
    Wu, Xiongwei
    Wu, Yuping
    CHINESE JOURNAL OF CHEMISTRY, 2017, 35 (12) : 1789 - 1796
  • [35] Ag Embedded Li3VO4 as Superior Anode for Li-Ion Batteries
    Kang, Tao
    Ni, Shibing
    Chen, Qichang
    Li, Tao
    Chao, Dongliang
    Yang, Xuelin
    Zhao, Jinbao
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (03) : A5295 - A5300
  • [36] Transport and structural properties of pure and Cr doped Li3VO4
    Massarotti, V
    Capsoni, D
    Bini, M
    Mustarelli, P
    Chiodelli, G
    Azzoni, CB
    Galinetto, P
    Mozzati, MC
    JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (31): : 14845 - 14851
  • [37] Growth and characterization of Li3VO4 single crystals by the Czochralski method
    Kim, DJ
    Kim, JS
    Kim, JN
    Jang, MS
    JOURNAL OF CRYSTAL GROWTH, 2000, 217 (04) : 383 - 387
  • [38] Rapid hydrothermal synthesis of Li3VO4 with different favored facets
    Yi Shi
    Yi Zhang
    Lili Liu
    Zhijia Zhang
    Jun Wang
    Shulei Chou
    Jie Gao
    Héctor D. Abruña
    Huijun Li
    Huakun Liu
    David Wexler
    Jiazhao Wang
    Yuping Wu
    Journal of Solid State Electrochemistry, 2017, 21 : 2547 - 2553
  • [39] OXYGEN-ASSOCIATED TRAPPED-HOLE CENTERS IN HIGH-PURITY FUSED SILICAS
    STAPELBROEK, M
    GRISCOM, DL
    FRIEBELE, EJ
    SIGEL, GH
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1979, 32 (1-3) : 313 - 326
  • [40] LATTICE DISTORTION AND ELECTRIC-FIELD GRADIENTS ABOUT TRAPPED-HOLE CENTERS IN MGO
    BASS, R
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1977, 22 (03): : 327 - 327
12345