SOLVENT-EXTRACTION OF PERTECHNETATE WITH TBP FROM PERCHLORIC-ACID SOLUTION

被引：8

作者：

OMORI, T ^{[1
]}

TADOKORO, M ^{[1
]}

SUZUKI, Y ^{[1
]}

SUGANUMA, H ^{[1
]}

YOSHIHARA, K ^{[1
]}

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 980,JAPAN

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES | 1994年 / 181卷 / 01期

关键词：

D O I：

10.1007/BF02037548

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Solvent extraction mechanism of pertechnetic acid with TBP from perchloric acid solutions is discussed. When cyclohexane is used as a diluent of TBP, perchloric acid can be extracted in the form of HClO4(TBP)2 into the organic phase. The TBP extraction of pertechnetic acid competes with perchloric acid and its equilibria are expressed as follows: HTcO4 + 3TBP reversible HTcO4(TBP)3 and HTcO4(TBP)3 + TBP reversible HTcO4(TBP)4.

引用

页码：71 / 76

页数：6

共 50 条

[41] Nitric Acid Extraction into the TODGA/TBP Solvent
McLachlan, Fiona
Greenough, Katie
Geist, Andreas
McLuckie, Bliss
Modolo, Giuseppe
Wilden, Andreas
Taylor, Robin
SOLVENT EXTRACTION AND ION EXCHANGE, 2016, 34 (04) : 334 - 346
[42] ANOMALOUS BEHAVIOR OF RADIOIODINE - SOLVENT-EXTRACTION FROM ACIDIC SOLUTION
TAKAHASHI, N
YANO, D
TAMIYA, Y
BABA, H
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS, 1995, 200 (05): : 417 - 426
[43] STUDY OF REACTION OF VICTORIA VIOLET PROTONIZATION IN PERCHLORIC-ACID SOLUTION
MASLOWSKA, J
ROCZNIKI CHEMII, 1972, 46 (02): : 277 - +
[44] CHEMISM OF INDIUM EXTRACTION BY DI-2-ETHYLHEXYLDITHIOPHOSPHORIC ACID FROM SULFURIC AND PERCHLORIC-ACID SOLUTIONS
LEVIN, IS
FRID, OM
RODINA, TF
ZHURNAL NEORGANICHESKOI KHIMII, 1977, 22 (10): : 2816 - 2821
[45] KINETICS OF CERIUM(IV) OXIDATION OF PROPIONIC-ACID IN PERCHLORIC-ACID - ROLE OF SOLVENT
ALVAREZMACHO, MP
MATAPEREZ, F
REACTION KINETICS AND CATALYSIS LETTERS, 1992, 48 (01): : 153 - 162
[46] COMPARISON OF METHANOL AND PERCHLORIC-ACID EXTRACTION PROCEDURES FOR ANALYSIS OF NUCLEOTIDES BY ISOTACHOPHORESIS
REIJENGA, JC
WES, JH
VANDONGEN, CAM
JOURNAL OF CHROMATOGRAPHY, 1986, 374 (01): : 162 - 169
[47] SOLVENT-EXTRACTION STUDIES ON THE RECOVERY OF PLUTONIUM(IV) FROM PHOSPHORIC-ACID SOLUTION USING MONOOCTYLPHENYLPHOSPHORIC ACID
SHIVARUDRAPPA, V
MITHAPARA, PD
JAIN, HC
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-ARTICLES, 1990, 141 (01): : 163 - 169
[48] REDUCTION OF CHLORATOPENTAAQUOCHROMIUM(III) ION BY CHROMIUM(II) IN PERCHLORIC-ACID SOLUTION
THOMPSON, RC
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1974, : 163 - 163
[49] SOLVENT-EXTRACTION SEPARATION OF LANTHANIDES FROM SILICIC-ACID
KALMYKOVA, IS
KUKARINA, LV
JOURNAL OF ANALYTICAL CHEMISTRY OF THE USSR, 1978, 33 (05): : 703 - 705
[50] RECOVERY OF EICOSAPENTAENOIC ACID FROM FUNGAL MYCELIA BY SOLVENT-EXTRACTION
OBRIEN, DJ
SENSKE, GE
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1994, 71 (09) : 947 - 950

← 1 2 3 4 5 →