VISCOSITY AND DENSITY OF BINARY-LIQUID MIXTURES OF TRI-N-BUTYL PHOSPHATE PLUS BENZENE, PLUS CARBON-TETRACHLORIDE, PLUS ISOBUTYL METHYL KETONE AND PLUS ACETYLACETONE AT 25-DEGREES-C, 30-DEGREES-C, 35-DEGREES-C, 40-DEGREES-C AND 45-DEGREES-C

被引:0
|
作者
ROUT, BK [1 ]
MISHRA, NC [1 ]
CHAKRAVORTTY, V [1 ]
机构
[1] UTKAL UNIV,DEPT CHEM,BHUBANESWAR 751004,ORISSA,INDIA
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中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Viscosities and densities of four binary mixtures tri-n-butyl phosphate+benzene, +carbon tetrachloride, +isobutyl methyl ketone and +acetylacetone have been measured at 25, 30, 40 and 45-degrees-C at six mole fractions of each mixture. From the experimental data excess viscosities DELTAln eta, excess Gibbs energies of activation DELTAG*E of flow, excess entropies of activation DELTAS*E of flow, and excess molar volume V(E) have been calculated. The molecular interactions in these mixtures are explained considering relative magnitude of these parameters.
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页码:347 / 350
页数:4
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