X-RAY K-ABSORPTION STUDIES OF SOME SCHIFF-BASE COPPER-COMPLEXES

被引：0
|
作者：
HANKARE, PP
BHASKARE, CK
机构：
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1994年 / 33卷 / 08期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chemical shifts and widths of copper K-edges are reported for some schiff base copper complexes by means of X-ray absorption spectroscopy in which a Cauchris type bend spectrograph has been utilized. The metal-ligand distances have been computed using Levy's method. The results arc examined to understand the nature of metal-ligand bonding. The observed linear relationships between chemical shifts (E, eV) and bond distance/(angstrom) and edge width and metal-ligand electronegative differences have been interpreted in terms of changes in the degree of covalency of the metal-ligand bonding in the synthesised copper complexes.
引用
收藏
页码：770 / 771
页数：2
相关论文
共 50 条
  • [31] X-RAY K-ABSORPTION SPECTRAL STUDIES OF SOME COPPER(II) MIXED-LIGAND COMPLEXES WITH GLYCINE AS PRIMARY LIGAND
    SHRIVASTAVA, BD
    MISHRA, A
    JOSHI, SK
    MANDLOI, SN
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1992, 31 (12): : 929 - 936
  • [32] X-RAY-DIFFRACTION STUDIES OF SOME THORIUM(IV) SCHIFF-BASE COMPLEXES
    GOUDAR, TR
    NADAGOUD, GS
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1988, 65 (09) : 666 - 667
  • [33] Correlation of Wiener indices with x-ray K-absorption parameters of some copper(II) and cobalt(II) complexes
    Mishra, A., 2000, John Wiley and Sons Ltd (29)
  • [34] X-ray diffraction and X-ray K-absorption near edge studies of Copper (II) Micro cyclic Carbamide complexes.
    Malviya, P.K.
    Sharma, P.
    Mishra, A.
    Bhalse, D.
    Journal of Physics: Conference Series, 2016, 755 (01):
  • [35] Correlation of Wiener indices with x-ray K-absorption parameters of some copper(II) and cobalt(II) complexes
    Mishra, A
    Pandey, D
    Dubey, R
    Kekre, PA
    Kumar, A
    X-RAY SPECTROMETRY, 2000, 29 (02) : 161 - 165
  • [36] X-RAY K-ABSORPTION STUDY OF COPPER IN MALACHITE MINERAL
    HEMACHANDRAN, K
    CHETAL, AR
    PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1986, 136 (01): : 181 - 185
  • [37] X-ray K-absorption near edge structure studies of some copper (II) mixed ligand complexes with alanine as primary ligand
    Mishra, A
    Dubey, R
    Pandey, D
    Kekre, PA
    Shrivastava, BD
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 1998, 36 (09) : 537 - 544
  • [38] X-RAY K-ABSORPTION EDGE ANALYSIS OF COBALT IN SOME COBALT COMPLEXES.
    Khadikar, Padmakar V.
    Pandharkar, Sadhana P.
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes, 1987, 26 (07): : 1146 - 1152
  • [39] CHEMICAL-SHIFT OF X-RAY K-ABSORPTION EDGE OF CO IN SOME COMPLEXES
    SINGH, MB
    RAI, SD
    SINGH, B
    NATIONAL ACADEMY SCIENCE LETTERS-INDIA, 1985, 8 (12): : 385 - 386
  • [40] X-Ray K-Absorption Fine Structure Studies of Some Copper(II) Mixed-Ligand Complexes with Alanine as Primary Ligand
    Mishra, Ashutosh
    Kekre, P.A.
    Dubey, Rajesh
    Shrivastava, B.D.
    X-Ray Spectrometry, 26 (02): : 75 - 78
12345