PHOTOLYSIS OF POLY(ETHYL ACRYLATE) AND POLY (NORMAL-BUTYL ACRYLATE) IN-VACUO

被引：9

作者：

MCGILL, WJ ^{[1
]}

ACKERMAN, L ^{[1
]}

机构：

[1] UNIV PORT ELIZABETH,MAT SCI DEPT,PORT ELIZABETH,SOUTH AFRICA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1974年 / 12卷 / 07期

关键词：

ALCOHOLS - CARBON MONOXIDE - CHEMICALS - POLYMERS - Photochemical Reactions - VACUUM TECHNOLOGY;

D O I：

10.1002/pol.1974.170120716

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thin films of poly(ethyl acrylate) and poly(n-butyl acrylate) were decomposed in vacuo by means of a high pressure Hg lamp, and the rate of development of volatile products was measured. The main gaseous products were CO, CO//2, and the alcohol, aldehyde, alkane, and formate derived from the respective ester groups. In addition poly(ethyl acrylate) evolved acetal as well as ethyl propionate, while n-butyl valerate was evolved from poly(n-butyl acrylate) only after prolonged exposure. All products and the principal features of the decomposition are discussed.

引用

页码：1541 / 1547

页数：7

共 50 条

[21] INTERPENETRATING POLYMER NETWORKS FROM CASTOR-OIL BASED POLYURETHANES AND POLY(NORMAL-BUTYL ACRYLATE)
PATEL, P
SUTHAR, B
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 1988, 12 (02) : 135 - 145
[22] PHOTOSYNTHESIS AND APPLICATION OF POLYFUNCTIONAL POLY(NORMAL-BUTYL ACRYLATE) ELASTOMERS FOR USE IN EPOXY-RESIN TOUGHENING
WANG, HB
LI, SJ
YE, JY
JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 44 (05) : 789 - 797
[23] Synthesis and characterization of poly methyl acrylate-poly ethyl acrylate copolymer
Leon, C.
Rodriguez, R.
Peralta, R.
Alvarez, C.
Castano, V.M.
International Journal of Polymeric Materials, 1997, 35 (1-4): : 119 - 128
[24] IMPACT PERFORMANCE OF EPOXY-RESINS WITH POLY(NORMAL-BUTYL ACRYLATE) AS THE REACTIVE LIQUID RUBBER MODIFIER
GAZIT, S
BELL, JP
ACS SYMPOSIUM SERIES, 1983, 221 : 69 - 83
[25] Synthesis and characterization of poly(butyl acrylate)/silica and poly(butyl acrylate)/silica/poly(methyl methacrylate) composite particles
Qi, DM
Bao, YZ
Huang, ZM
Weng, ZX
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 99 (06) : 3425 - 3432
[26] PHOTOLYSIS OF POLY(METHYL ACRYLATE) IN OXYGEN
ACKERMAN, L
MCGILL, WJ
JOURNAL OF THE SOUTH AFRICAN CHEMICAL INSTITUTE, 1974, 27 (03): : 105 - 110
[27] PHOTOLYSIS OF POLY(METHYL ACRYLATE) IN VACUUM
ACKERMAN, L
MCGILL, WJ
JOURNAL OF THE SOUTH AFRICAN CHEMICAL INSTITUTE, 1973, 26 (03): : 82 - 93
[28] PHOTOLYSIS OF POLY(METHYL ACRYLATE) IN SOLUTION
GRASSIE, N
DAVIS, TI
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1974, 175 (09): : 2657 - 2667
[29] TENSILE PROPERTIES OF BLENDS OF COPOLYMERS OF NORMAL-BUTYL METHACRYLATE WITH ETHYL ACRYLATE AND CHLORINATED RUBBER
PITCHUMANI, S
REDDY, CR
RAJADURAI, S
JOSEPH, KT
SANTAPPA, M
EUROPEAN POLYMER JOURNAL, 1982, 18 (11) : 949 - 952
[30] Miscibility of poly(ethyl acrylate-co-acrylate) ionomers with poly(ethyl acrylate-co-itaconate) ionomers.
Song, JM
Jeon, HS
Kim, JS
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : C114 - C114

← 1 2 3 4 5 →