OPTICAL METAL-TO-METAL CHARGE-TRANSFER OF (MU-CYANO)DECAAMMINEDIOSMIUM(III)

被引:5
|
作者
KUNKELY, H [1 ]
PAWLOWSKI, V [1 ]
VOGLER, A [1 ]
机构
[1] UNIV REGENSBURG,INST ANORGAN CHEM,D-93040 REGENSBURG,GERMANY
关键词
CHARGE TRANSFER EXCITATION; OSMIUM COMPLEXES; AMMINE COMPLEXES; CYANO-BRIDGED COMPLEXES;
D O I
10.1016/0020-1693(95)04740-Z
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The binuclear complex [(NH3)(5)Os-III(mu-CN)Os-III(NH3)(5)](5+) shows absorption bands in the visible region (at lambda(max) = 523, 425 and 326 nm) which are assigned to Os(III)-to-Os(III) metal-to-metal charge transfer (MMCT) transitions.
引用
收藏
页码:1 / 3
页数:3
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