CU-63 AND AG-109 NMR-STUDIES OF COPPER(I) AND SILVER(I) SALTS IN MIXED-SOLVENTS CONTAINING NITRILES

被引：36

作者：

GILL, DS ^{[1
]}

RODEHUSER, L ^{[1
]}

RUBINI, P ^{[1
]}

DELPUECH, JJ ^{[1
]}

机构：

[1] UNIV NANCY 1,ETUDES SYST ORGAN & COLLOIDAUX LAB,CNRS,URA 406,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 15期

关键词：

D O I：

10.1039/ft9959102307

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solvation of copper(I) in mixed solvent systems containing acetonitrile or benzonitrile and the co-solvents propionitrile, butyronitrile, valeronitrile, as well as trimethyl-, triethyl- and tributyl-phosphite has been examined by Cu-63 NMR and also, in the case of the phosphites, by P-31 NMR. The concentration dependence and the variation of the chemical shift of the silver-109 signal with solvent composition have been studied in solutions of silver trifluoroacetate (AgO2CCF3).

引用

页码：2307 / 2312

页数：6

共 45 条

[41] Synthesis and luminescence behaviour of mixed-metal rhenium(I)-copper(I) and -silver(I) alkynyl complexes.: X-Ray crystal structures of [{η2-Re(Co)3(bpy)(CCPh)}2Cu]PF6 and [{η2-Re(CO)3(bpy)(CCPH)}2Ag]PF6
Yam, VWW
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CHEMICAL COMMUNICATIONS, 1999, (11) : 1013 - 1014
[42] Structural characterization of 1:1 adducts of silver(I) (pseudo-) halides (AgX, X = NCO, Cl, Br, I) with Ph2E(CH2)EPh2 (E= P, As) ('dp(p/a)m') and 4:3 adducts of copper(I) halide (CuX, X = Cl, Br, I), containing trinuclear cations, of the form [X2Ag3(dppm)3]X and [X2Cu3(dppm)3](CuX2) and the novel neutral [(OCN)3Ag3(dpam)3]
Di Nicola, C
Effendy
Fazaroh, F
Pettinari, C
INORGANICA CHIMICA ACTA, 2005, 358 (03) : 720 - 734
[43] SYNTHESIS AND MULTINUCLEAR NMR-STUDIES ON COPPER AND SILVER COMPLEXES OF MULTIDENTATE PHOSPHINE AND MIXED PHOSPHA/THIA LIGANDS - SINGLE-CRYSTAL STRUCTURE OF [CU(P2S2)]PF6 (P2S2=PH(2)PCH(2)CH(2)SCH(2)CH(2)SCH(2)CH(2)PPH(2))
DOEL, CL
GIBSON, AM
REID, G
FRAMPTON, CS
POLYHEDRON, 1995, 14 (20-21) : 3139 - 3146
[44] Silver(I) nitrate adducts with bidentate 2-, 3- and 4-pyridyl phosphines.: Solution 31P and [31P-109Ag] NMR studies of 1:2 complexes and crystal structure of dimeric [{Ag(d2pype)(μ-d2pype)}2]-[NO3]2•2CH2Cl2 [d2pype = 1,2-bis(di-2-pyridylphosphino)ethane]
Berners-Price, SJ
Bowen, RJ
Harvey, PJ
Healy, PC
Koutsantonis, GA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (11): : 1743 - 1750
[45] Homoleptic copper(I) and silver(I) complexes with o-phenylene-backboned bis(thioethers), bis(selenoethers), and bis(telluroethers): Synthesis, multinuclear NMR studies, and crystal structures of [Cu{o-C6H4(SeMe)(2)}(2)]PF6, [Cu{o-C6H4(TeMe)(2)}(2)]PF6, and [Ag-n{mu-o-C6H4(SeMe)(2)}(n){o-C6H4(SeMe)(2)}(n)][BF4](n)center dot nCH(2)Cl(2)
Black, JR
Champness, NR
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INORGANIC CHEMISTRY, 1996, 35 (07) : 1820 - 1824

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