MONTE-CARLO SIMULATIONS OF ADSORBED RANDOM COPOLYMERS

被引：38
|
作者：
COSGROVE, T
FINCH, NA
WEBSTER, JRP
机构：
[1] School of Chemistry, University of Bristol, Cantock’s Close
[2] ICI Pharmaceuticals PLC, Alderley Edge, Cheshire
来源：
MACROMOLECULES | 1990年 / 23卷 / 13期
关键词：
D O I：
10.1021/ma00215a023
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A Monte Carlo method is described for simulating the conformations of random copolymers at the solid/solvent interface. The effects of solvency, preferential adsorption, chain length, and coverage are considered. The effects of varying the point of attachment, the chain composition, and the cell boundary are discussed. Volume fraction profiles normal and parallel to the surface are calculated and comparisons are made with experimental data from small-angle neutron scattering (SANS). © 1990, American Chemical Society. All rights reserved.
引用
收藏
页码：3353 / 3357
页数：5
相关论文
共 50 条
  • [11] MONTE-CARLO SIMULATIONS OF MICROEMULSIONS
    BOYDEN, S
    JAN, N
    RAY, T
    NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1994, 16 (09): : 1439 - 1445
  • [12] MONTE-CARLO SIMULATIONS OF ZEOLITES
    SOUKOULIS, CM
    JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (21): : 4898 - 4901
  • [13] PARALLEL MONTE-CARLO SIMULATIONS
    ESSELINK, K
    LOYENS, LDJC
    SMIT, B
    PHYSICAL REVIEW E, 1995, 51 (02): : 1560 - 1568
  • [14] MULTICANONICAL MONTE-CARLO SIMULATIONS
    BERG, BA
    INTERNATIONAL JOURNAL OF MODERN PHYSICS C-PHYSICS AND COMPUTERS, 1993, 4 (02): : 249 - 256
  • [15] ON OPTIMIZATION OF MONTE-CARLO SIMULATIONS
    KOLAFA, J
    MOLECULAR PHYSICS, 1988, 63 (04) : 559 - 579
  • [16] OPTIMIZATION OF MONTE-CARLO SIMULATIONS
    HEUER, HO
    PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 1992, 182 (04) : 649 - 671
  • [17] AN INTRODUCTION TO MONTE-CARLO SIMULATIONS
    JOY, DC
    EUREM 88, VOLS 1-3: TUTORIALS, INSTRUMENTATION AND TECHNIQUES / PHYSICS AND MATERIALS / BIOLOGY, 1988, 93 : 23 - 32
  • [18] FASTER MONTE-CARLO SIMULATIONS
    BLUE, JL
    BEICHL, I
    SULLIVAN, F
    PHYSICAL REVIEW E, 1995, 51 (02) : R867 - R868
  • [19] Monte-Carlo simulations of thermal desorption of adsorbed molecules from metal surfaces
    Raaen, S
    Ramstad, A
    ENERGY, 2005, 30 (06) : 821 - 830
  • [20] Monte Carlo Simulations of Strong Memory Effect of Crystallization in Random Copolymers
    Gao, Huanhuan
    Vadlamudi, Madhavi
    Alamo, Rufina G.
    Hu, Wenbing
    MACROMOLECULES, 2013, 46 (16) : 6498 - 6506
12345