BIOCATALYTIC RESOLUTION OF TERTIARY ALPHA-SUBSTITUTED CARBOXYLIC-ACID ESTERS - EFFICIENT PREPARATION OF A QUATERNARY ASYMMETRIC CARBON CENTER

被引：25

作者：

YEE, C ^{[1
]}

BLYTHE, TA ^{[1
]}

MCNABB, TJ ^{[1
]}

WALTS, AE ^{[1
]}

机构：

[1] GENZYME CORP, 1 KENDALL SQ, CAMBRIDGE, MA 02139 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 13期

关键词：

D O I：

10.1021/jo00039a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method for resolving a variety of tertiary alpha-substituted carboxylic acid

引用

页码：3525 / 3527

页数：3

共 26 条

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[22] Rh-catalyzed asymmetric hydrogenation of γ-phthalimido-substituted α,β-unsaturated carboxylic acid esters:: An efficient enantioselective synthesis of β-aryl-γ-amino acids (vol 9, pg 4827, 2007)
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[23] Asymmetric synthesis of both enantiomers of esters and γ-lactones from opticafly active 1-chlorovinyl p-tolyl sulfoxides and lithium ester enolates with the formation of a tertiary or a quaternary carbon stereogenic center at the β-position
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Satoh, T
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[24] NEW REACTIONS OF POTASSIUM NAPHTHALENIDE WITH BETA-LACTONES, GAMMA-LACTONES AND DELTA-LACTONES - AN EFFICIENT ROUTE TO ALPHA-ALKYL GAMMA-LACTONES AND DELTA-LACTONES AND ALPHA,BETA-UNSATURATED CARBOXYLIC-ACID ESTERS
KOWALCZUK, M
KURCOK, P
GLOWKOWSKI, W
JEDLINSKI, Z
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (01): : 389 - 391
[25] Rhodium-catalyzed enantioselective Michael addition of (1-cyanoethyl)phosphonate: Synthesis of optically active phosphonic acid derivatives with phosphorus-substituted quaternary asymmetric carbon center
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Hamashima, H
Ito, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (11) : 2559 - 2562
[26] Asymmetric synthesis of carboxylic acid derivatives having an all-carbon α-quaternary center through Cu-catalyzed 1,4-addition of dialkylzinc reagents to 2-aryl acetate derivatives
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Fillion, Eric
ORGANIC LETTERS, 2008, 10 (13) : 2801 - 2804

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