DIOXYGEN ACTIVATION BY ACETYLACETONE AND SALICYLALDEHYDE COMPLEXES OF FE(II)

被引：1
|
作者：
DHAR, SK
PARK, BJ
ARNOLD, C
机构：
[1] De Paul Univ, Dept Chem, Chicago
来源：
MICROCHEMICAL JOURNAL | 1993年 / 47卷 / 1-2期
关键词：
D O I：
10.1006/mchj.1993.1004
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Acetylacetone and salicylaldehyde complexes of Fe(II), formed by mixing ferrous per-chlorate with the complexing ligands in the presence of a base, such as pyridine or an amide, show autoxidation in a wide range of solvents including water. The reaction takes place by a nonradical mechanism. © 1993 Academic Press. All rights reserved.
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页码：14 / 18
页数：5
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