AN EFFICIENT PROCEDURE FOR THE SYNTHESIS OF C-CHIRAL BISPHOSPHINES

被引：97
|
作者：
MCKINSTRY, L [1 ]
LIVINGHOUSE, T [1 ]
机构：
[1] MONTANA STATE UNIV,DEPT CHEM & BIOCHEM,BOZEMAN,MT 59717
来源：
TETRAHEDRON | 1995年 / 51卷 / 28期
关键词：
D O I：
10.1016/0040-4020(95)00390-T
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A practical method for the synthesis of bisphosphines containing homochiral carbon backbones is described. This procedure entails sequential reaction of a homochiral ditosylate with the appropriate dialkyl- or diarylphosphine-borane anion followed by BH5 decomplexation mediated by HBF4 . OMe(2).
引用
收藏
页码：7655 / 7666
页数：12
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