THE EFFICIENT DEPROTECTION OF ACETALS AND TETRAHYDROPYRANYL DERIVATIVES OF PHENOLS USING [RU(CH3CN)(3)(TRIPHOS)](OTF)(2) AS A CATALYST

被引：27
|
作者：
MA, SM [1 ]
VENANZI, LM [1 ]
机构：
[1] ETH ZENTRUM,ANORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND
来源：
TETRAHEDRON LETTERS | 1993年 / 34卷 / 50期
关键词：
D O I：
10.1016/S0040-4039(00)61453-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acetals and tetrahydropyranyl derivatives of phenols are efficiently and highly chemoselectively deprotected in the presence of catalytic amounts of [Ru(CH3CN)(3)(triphos)]-(OTf)(2) (triphos = CH3C(CH(2)PPh(2))(3)), under mild condition, in good to excellent yields.
引用
收藏
页码：8071 / 8074
页数：4
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