CRYSTAL-STRUCTURE OF BETA'-FE0.33V2O5

被引：6
|
作者：
PERMER, L [1 ]
FEREY, G [1 ]
机构：
[1] UNIV MAINE,FAC SCI,FLUORURES LAB,CNRS,URA 449,AVE OLIVIER MESSIAEN,F-72017 LE MANS,FRANCE
来源：
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1994年 / 209卷 / 05期
关键词：
MIXED VALENCE;
D O I：
10.1524/zkri.1994.209.5.413
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Fe0.33V2O5 crystallizes in the monoclinic space group C2/m with a = 15.307(8) angstrom, b = 3.624(2) angstrom, c = 10.123(5) angstrom, beta = 107.30(3)degrees, V = 536.12 angstrom3, and Z = 6. The structure was determined from single crystal X-ray diffraction data and it is related to the beta'-MxV2O5 structure type. There are some indications of partial cationic order between V4+ and V5+ within the three vanadium sites. Fe2+ occupies two crystallographic sites with tetrahedral and 3 + 1 coordination, respectively.
引用
收藏
页码：413 / 417
页数：5
相关论文
共 50 条
  • [31] CRYSTAL-STRUCTURE OF AS2O5, A NEW TYPE OF FRAMEWORK STRUCTURE
    JANSEN, M
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1978, 441 (04): : 5 - 12
  • [32] SYNTHESIS AND CRYSTAL-STRUCTURE OF BAPTEU2O5 AND BANIEU2O5
    MULLERBUSCHBAUM, H
    LANG, C
    JOURNAL OF THE LESS-COMMON METALS, 1988, 142 (1-2): : L1 - L3
  • [33] CRYSTAL-STRUCTURE OF V4O7
    HORIUCHI, H
    TOKONAMI, M
    NAGASAWA, K
    MORIMOTO, N
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (MAY15): : 1404 - &
  • [34] CRYSTAL-STRUCTURE OF V3O7
    WALTERSS.K
    FORSLUND, B
    WILHELMI, KA
    ANDERSSO.S
    GALY, J
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1974, 30 (NOV15): : 2644 - 2651
  • [35] CRYSTAL-STRUCTURE OF VERY SMALL PARTICLES OF CR, V AND FE
    KIMOTO, K
    NISHIDA, I
    ACTA CRYSTALLOGRAPHICA SECTION A, 1972, 28 : S131 - S131
  • [36] CRYSTAL-STRUCTURE OF V3RH5
    WATERSTRAT, RM
    DICKENS, B
    JOURNAL OF THE LESS-COMMON METALS, 1973, 31 (01): : 61 - 67
  • [37] CRYSTAL-STRUCTURE OF BETA-CACRO4,2H2O
    AMOR, MB
    LOUER, M
    LEMAROUILLE, JY
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1982, 294 (12): : 725 - 728
  • [38] CRYSTAL-STRUCTURE OF BETA-NASBS2
    VOLK, K
    SCHAFER, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1978, 33 (08): : 827 - 828
  • [39] THE CRYSTAL-STRUCTURE OF CA5RE2O12
    MONS, HA
    JEITSCHKO, W
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1986, 174 (1-4): : 149 - 149
  • [40] CRYSTAL-STRUCTURE OF BETA-RBSCO2
    WIENCH, H
    BRACHTEL, G
    HOPPE, R
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 436 (DEC): : 169 - 172
12345