PYRAZOLONE AZOMETHINE DYES AS EFFECTIVE PHOTOINITIATORS OF FREE-RADICAL POLYMERIZATION

被引：21
|
作者：
KUCYBALA, Z [1 ]
PACZKOWSKI, J [1 ]
机构：
[1] TECH & AGR UNIV,DEPT CHEM & CHEM ENGN,SEMINARYJNA 3,PL-85326 BYDGOSZCZ,POLAND
来源：
POLYMER | 1993年 / 34卷 / 07期
关键词：
DYE INITIATING SYSTEM; PYRAZOLONE AZOMETHINE DYES;
D O I：
10.1016/0032-3861(93)90883-C
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new class of free radical photoinitiators based on pyrazolone azomethine dyes has been investigated. Results show that the free radical formation occurs via intermolecular electron transfer. Changes in the dye structures are translated into changes in the rate of polymerization. Dyes which have electron withdrawing substituents initiate the free radical polymerization more readily than those with electron releasing groups. The introduction of heavy atoms into the dye molecule decreases the rate of initiation of free radical polymerization.
引用
收藏
页码：1558 / 1560
页数：3
相关论文
共 50 条
  • [31] FREE-RADICAL POLYMERIZATION OF PHENYLACETYLENE
    AMDUR, S
    CHENG, ATY
    WONG, CJ
    EHRLICH, P
    ALLENDOERFER, RD
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1978, 16 (02) : 407 - 414
  • [32] FREE-RADICAL INITIATED POLYMERIZATION
    PERCEC, V
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 188 (AUG): : 3 - POLY
  • [33] FREE-RADICAL POLYMERIZATION OF ACRYLAMIDE
    SILVERSMITH, EF
    WOLSEY, WC
    JOURNAL OF CHEMICAL EDUCATION, 1992, 69 (09) : 763 - 763
  • [34] NITROXIDE STABLE FREE-RADICAL MEDIATED FREE-RADICAL POLYMERIZATION - AUTOPOLYMERIZATION
    GEORGES, MK
    VEREGIN, RPN
    KAZMAIER, PM
    HAMER, GK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 491 - POLY
  • [35] New 1,8-Naphthalimide Derivatives as Photoinitiators for Free-Radical Polymerization Upon Visible Light
    Bonardi, Aude-Heloise
    Zahouily, Soraya
    Dietlin, Celine
    Graff, Bernadette
    Morlet-Savary, Fabrice
    Ibrahim-Ouali, Malika
    Gigmes, Didier
    Hoffmann, Norbert
    Dumur, Frederic
    Lalevee, Jacques
    CATALYSTS, 2019, 9 (08)
  • [36] PARA-PARA'-BIS((TRIPHENYLPHOSPHONIO)METHYL)BENZOPHENONE SALTS AS PHOTOINITIATORS OF FREE-RADICAL AND CATIONIC POLYMERIZATION
    NECKERS, DC
    ABUABDOUN, II
    MACROMOLECULES, 1984, 17 (12) : 2468 - 2473
  • [37] Designing free-radical redox photoinitiators for practical dark curing
    Kim, Kangmin
    Sinha, Jasmine
    Musgrave, Charles
    Stansbury, Jeffrey
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [38] TEMPLATE POLYMERIZATION BY FREE-RADICAL MECHANISMS
    TAN, YY
    CHALLA, G
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1987, 10 : 215 - 233
  • [39] Modeling stable free-radical polymerization
    Zhu, SP
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1999, 37 (18) : 2692 - 2704
  • [40] FREE-RADICAL INITIATED POLYMERIZATION OF DIETHYLFUMARATE
    BENGOUGH, WI
    PARK, GB
    YOUNG, RA
    EUROPEAN POLYMER JOURNAL, 1975, 11 (04) : 305 - 308
12345