PREPARATION AND X-RAY STRUCTURES OF GOLD(I) COMPLEXES WITH SOME FLUOROPHOSPHORUS (III) LIGANDS

被引：0
|
作者：
LIN, Y [1 ]
JONES, PG [1 ]
SCHMUTZLER, R [1 ]
SHELDRICK, GM [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1992年 / 29卷 / 4-5期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of complexes [(L)AuCl] of gold(I) with fluorophosphorus(III) ligands L was obtained by displacing tetrahydrothiophene (tht) from the complex [(tht)AuCl] with the appropriate ligand. The products were characterised by F-19 and P-31 n.m.r. spectroscopy and in two cases by single crystal X-ray studies. The molecule of [(Me2NPF2)AuCl] 3 displays crystallographic mirror symmetry, with short Au...Au contacts (334 pm) between molecules. In [(2,5-Me2C6H3PF2)AuCl] 2 there is no imposed symmetry and the shortest Au...Au contacts are 370 pm.
引用
收藏
页码：887 / 898
页数：12
相关论文
共 50 条
  • [31] X-ray structures of chromatin complexes
    Luger, K
    Tan, S
    Mader, A
    Richmond, TJ
    PROGRESS IN BIOPHYSICS & MOLECULAR BIOLOGY, 1996, 65 : SD102 - SD102
  • [32] Validation of ligands in X-ray crystal structures
    Malde, Alpeshkumar K.
    Mark, Alan E.
    JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS, 2015, 33 : 117 - 117
  • [33] SOME NEW GOLD(I) COMPLEXES WITH BULKY LIGANDS
    BANDITELLI, G
    BANDINI, AL
    BONATI, F
    GOEL, RG
    MINGHETTI, G
    GAZZETTA CHIMICA ITALIANA, 1982, 112 (11-1): : 539 - 542
  • [34] Organogold(I) complexes:: Synthesis, X-ray crystal structures and aurophilicity
    Croix, C
    Balland-Longeau, A
    Allouchi, H
    Giorgi, M
    Duchêne, A
    Thibonnet, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (21-22) : 4835 - 4843
  • [35] GOLD COMPLEXES WITH SELENIUM LIGANDS .4. PREPARATION, CRYSTAL-STRUCTURES AND REACTIONS OF PHOSPHINE(SELENOUREA)GOLD(I) COMPLEXES
    JONES, PG
    THONE, C
    CHEMISCHE BERICHTE-RECUEIL, 1991, 124 (12): : 2725 - 2729
  • [36] GOLD(III)-CYCLAM COMPLEXES - X-RAY CRYSTAL-STRUCTURE AND A USEFUL MACROCYCLIC EFFECT ON THE REDUCTION OF GOLD(III)
    KIMURA, E
    KUROGI, Y
    KOIKE, T
    SHIONOYA, M
    IITAKA, Y
    JOURNAL OF COORDINATION CHEMISTRY, 1993, 28 (01) : 33 - 49
  • [37] X-RAY LIII-ABSORPTION EDGES OF GOLD AND PLATINUM IN SOME COMPLEXES
    DEODHAR, GB
    NIGAM, AN
    NATURWISSENSCHAFTEN, 1958, 45 (13) : 309 - 309
  • [38] Characterization and X-Ray Structures of Oxovanadium(V) Complexes Derived from Hydrazone Ligands
    X.-Z. Zhang
    X.-F. Chen
    C. Li
    S. Kong
    H.-H. Li
    Z. You
    H.-L. Zhu
    Journal of Structural Chemistry, 2018, 59 : 697 - 702
  • [39] Characterization and X-Ray Structures of Oxovanadium(V) Complexes Derived from Hydrazone Ligands
    Zhang, X. -Z.
    Chen, X. -F.
    Li, C.
    Kong, S.
    Li, H. -H.
    You, Z.
    Zhu, H. -L.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (03) : 697 - 702
  • [40] PREPARATION AND X-RAY CRYSTAL-STRUCTURES OF COPPER(I) COMPLEXES OF THE S3N- ION
    BOJES, J
    CHIVERS, T
    CODDING, PW
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (22) : 1171 - 1173
12345