PREPARATION AND X-RAY STRUCTURES OF GOLD(I) COMPLEXES WITH SOME FLUOROPHOSPHORUS (III) LIGANDS

被引：0
|
作者：
LIN, Y [1 ]
JONES, PG [1 ]
SCHMUTZLER, R [1 ]
SHELDRICK, GM [1 ]
机构：
[1] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1992年 / 29卷 / 4-5期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of complexes [(L)AuCl] of gold(I) with fluorophosphorus(III) ligands L was obtained by displacing tetrahydrothiophene (tht) from the complex [(tht)AuCl] with the appropriate ligand. The products were characterised by F-19 and P-31 n.m.r. spectroscopy and in two cases by single crystal X-ray studies. The molecule of [(Me2NPF2)AuCl] 3 displays crystallographic mirror symmetry, with short Au...Au contacts (334 pm) between molecules. In [(2,5-Me2C6H3PF2)AuCl] 2 there is no imposed symmetry and the shortest Au...Au contacts are 370 pm.
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页码：887 / 898
页数：12
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