FORMATION OF DIMETHYLAMINE COMPLEXES OF TRIMETHYLPLATINUM(IV) FROM REACTIONS WITH N,N,N',N'-TETRAMETHYLDIAMINOMETHANE

被引：5

作者：

ABEL, EW ^{[1
]}

GOLDSWORTHY, DH ^{[1
]}

HEARD, PJ ^{[1
]}

KITE, K ^{[1
]}

机构：

[1] UNIV EXETER, DEPT CHEM, EXETER EX4 4QD, DEVON, ENGLAND

来源：

POLYHEDRON | 1995年 / 14卷 / 04期

关键词：

D O I：

10.1016/0277-5387(94)00268-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Attempts to prepare complexes of trimethylplatinum(IV) with N,N,N',N'-tetra-methyldiaminomethane (TMDM) as either a chelating or bridging ligand gave only the complexes of dimethylamine [PtMe(3)X(HNMe(2))](2), (X = Cl, Br and I; 1-3 and [PtMe(3)(2,2'-bipyridyl)(HNMe(2))](+)[BF4](+) (4). H-1 NMR evidence showed that only one of the two possible isomers was formed for 1-3.

引用

页码：515 / 519

页数：5

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