FORMATION OF DIMETHYLAMINE COMPLEXES OF TRIMETHYLPLATINUM(IV) FROM REACTIONS WITH N,N,N',N'-TETRAMETHYLDIAMINOMETHANE

被引：5
|
作者：
ABEL, EW [1 ]
GOLDSWORTHY, DH [1 ]
HEARD, PJ [1 ]
KITE, K [1 ]
机构：
[1] UNIV EXETER, DEPT CHEM, EXETER EX4 4QD, DEVON, ENGLAND
来源：
POLYHEDRON | 1995年 / 14卷 / 04期
关键词：
D O I：
10.1016/0277-5387(94)00268-J
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Attempts to prepare complexes of trimethylplatinum(IV) with N,N,N',N'-tetra-methyldiaminomethane (TMDM) as either a chelating or bridging ligand gave only the complexes of dimethylamine [PtMe(3)X(HNMe(2))](2), (X = Cl, Br and I; 1-3 and [PtMe(3)(2,2'-bipyridyl)(HNMe(2))](+)[BF4](+) (4). H-1 NMR evidence showed that only one of the two possible isomers was formed for 1-3.
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页码：515 / 519
页数：5
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