ASYMMETRIC ALKYLATION OF CHIRAL ALPHA,BETA-UNSATURATED LACTONES

被引：13
|
作者：
KATO, K [1 ]
SUEMUNE, H [1 ]
SAKAI, K [1 ]
机构：
[1] KYUSHU UNIV,FAC PHARMACEUT SCI,FUKUOKA 812,JAPAN
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期
关键词：
(S,S)-CYCLOPENPANE-1,2-DIOL; (S,S)-CYCLOHEXANE-1,2-DIOL; ASYMMETRIC ALKYLATION; CHIRAL CYCLIC DIOL; CHIRAL AUXILIARY; 2,3-DIHYDRO-1,4-DIOXEPIN-5-ONE;
D O I：
10.1016/S0040-4039(00)92668-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkylation of 5, prepared from six-membered beta-keto ester and (S,S)-cyclohexane-1,2-diol, proceeded in highly diastereoselective manner to afford a quaternary carbon.
引用
收藏
页码：3481 / 3482
页数：2
相关论文
共 50 条
  • [31] REGIO AND STEREOSPECIFIC SYNTHESIS OF ALPHA,BETA-UNSATURATED ESTERS LACTONES AND ACIDS
    LUCCHETTI, J
    KRIEF, A
    TETRAHEDRON LETTERS, 1978, (30) : 2693 - 2696
  • [32] ASYMMETRIC MICHAEL ADDITIONS TO ALPHA,BETA-UNSATURATED OXAZOLINES - AN EFFICIENT PREPARATION OF CHIRAL BETA,BETA-DISUBSTITUTED PROPIONALDEHYDES
    MEYERS, AI
    SHIPMAN, M
    JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (25): : 7098 - 7102
  • [33] ELECTROCHEMICAL REDUCTIVE ALKYLATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
    TROLL, T
    ELBE, W
    OLLMANN, GW
    TETRAHEDRON LETTERS, 1981, 22 (31) : 2961 - 2964
  • [34] EFFICIENT CONJUGATE ALKYLATION OF ALPHA,BETA-UNSATURATED NITRO OLEFINS BY TRIORGANOALANES
    PECUNIOSO, A
    MENICAGLI, R
    JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (01): : 45 - 49
  • [35] ALKYLATION OF ALPHA,BETA-UNSATURATED AMIDES VIA METALATED AND DIMETALATED INTERMEDIATES
    OAKLEAF, JA
    THOMAS, MT
    WU, A
    SNIECKUS, V
    TETRAHEDRON LETTERS, 1978, (19) : 1645 - 1648
  • [36] ALKYLATION OF CYCLIC ALPHA,BETA-UNSATURATED KETONES AT THE DOUBLE-BOND
    WEBER, W
    KRAUS, W
    SPITZNER, D
    CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (01): : 385 - 390
  • [37] DOUBLE ALKYLATION OF ALPHA,BETA-UNSATURATED ACETALS - AN INVERSE POLARITY APPROACH
    YANAGISAWA, A
    HABAUE, S
    YAMAMOTO, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 366 - 368
  • [38] GENERAL METHOD FOR GAMMA-ALKYLATION OF ALPHA,BETA-UNSATURATED KETONES
    LANSBURY, PT
    ERWIN, RW
    TETRAHEDRON LETTERS, 1978, (30) : 2675 - 2678
  • [39] GAMMA-ALKYLATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
    WENKERT, E
    GOODWIN, TE
    RANU, BC
    JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (12): : 2137 - 2141
  • [40] ASYMMETRIC PHOTOCYCLIZATION OF N-ALPHA,BETA-UNSATURATED ACYLANILIDES
    NAITO, T
    TADA, Y
    NINOMIYA, I
    HETEROCYCLES, 1984, 22 (02) : 237 - 240
12345