NOVEL ONE-POT SYNTHESIS OF TETRASUBSTITUTED PHENOLIC KETONES AND SULFONES

被引：3

作者：

RAJAKUMAR, P

SATHEESHKUMAR, K

机构：

[1] Department of Organic Chemistry, University of Madras

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 17期

关键词：

D O I：

10.1080/00397919508011800

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of tetrasubstituted cyclopentadienones 1,1a with phenacyl bromide 2, dichloroacetophenone 3, ethyl bromomalonate 4, bromomethyl-p-tolylsulphone 5 in 50% NaOH and in the presence of benzyltriethylammonium chloride gave the carbene adduct 6,7,7a as well as pentasubstituted phenols 8,9,9a,10,10a,11,11a. The carbene adducts 6,7 and 7a were also converted into the phenols 8,9,9a using t-BuOK or NaOH in refluxing t-BuOH.

引用

页码：2561 / 2568

页数：8

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