SYNTHESIS AND CHARACTERIZATION OF POLY(ACRYLONITRILE)-BLOCK-POLY(ETHYLENE GLYCOL)-BLOCK-POLY(ACRYLONITRILE) COPOLYMER

被引:0
|
作者
NAGARAJAN, S [1 ]
SRINIVASAN, KSV [1 ]
机构
[1] CENT LEATHER RES INST,DIV POLYMER,MADRAS 600020,TAMIL NADU,INDIA
关键词
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The polymerization of acrylonitrile initiated by a new redox couple, Cerium(IV)-poly(ethylene glycol) [PEG, molecular weight 6000] in aqueous sulphuric acid medium at 50-degrees-C has been studied. The precipitated polymer which is a block copolymer of PEG and poly(acrylonitrile) has been characterized by means of FT-IR, H-1 NMR and Light Scattering measurements. The thermal behaviour of the polymer has been studied using DSC and TGA.
引用
收藏
页码:397 / 405
页数:9
相关论文
共 50 条
  • [21] Synthesis, Characterization, and Applications of Poly(ethylene glycol)-block-poly(ether-sulfide) Dendrimers
    Dowler, Wesley
    Robison, Jacob
    Fury, Jonathan
    Dou, Xiaozheng
    Delong, Robert
    Sedaghat-Herati, Reza
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2015, 52 (01): : 30 - 38
  • [22] Synthesis of poly(butylene terephthalate)-block-poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) multiblock terpolymers via a facile PROP method
    Zhang, Minzhi
    Gu, Jiali
    Zhu, Xiang
    Gao, Lingfeng
    Li, Xiaohong
    Yang, Xiaoming
    Tu, Yingfeng
    Li, Christopher Y.
    POLYMER, 2017, 130 : 199 - 208
  • [23] Poly(ε-caprolactone)-block-poly(ethylene glycol)-block-poly (ε-caprolactone)-based hybrid polymer electrolyte for lithium metal batteries
    Zuo, Cai
    Chen, Gong
    Zhang, Yong
    Gan, Huihui
    Li, Shaoqiao
    Yu, Liping
    Zhou, Xingping
    Xie, Xiaolin
    Xue, Zhigang
    JOURNAL OF MEMBRANE SCIENCE, 2020, 607
  • [24] Morphological control of poly(ethylene glycol)-block-poly(ε-caprolactone) copolymer aggregates in aqueous solution
    Fairley, Nichole
    Hoang, Bryan
    Allen, Christine
    BIOMACROMOLECULES, 2008, 9 (09) : 2283 - 2291
  • [25] Chitosan/poly(ε-caprolactone)-block-poly(ethylene glycol) copolymer electrospun membrane for the adsorption of dyes
    Chen, Jiaqi
    Xiang, Chunhui
    He, Nana
    Zhang, Junhao
    Li, Lili
    Dong, Shujun
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (46) : 20458 - 20469
  • [26] Double stimuli responsive mixed aggregates from poly(acrylic acid)-block-poly(ε-caprolactone)-block-poly(acrylic acid) and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymers
    Kamenova, Katya
    Trzebicka, Barbara
    Momekova, Denitsa
    Petrov, Petar
    POLYMER BULLETIN, 2017, 74 (03) : 707 - 720
  • [27] Nanostructured thermosetting blends of phenolic thermosets and poly(ethylene oxide)-block-poly(propylene oxide)-block-poly(ethylene oxide) triblock copolymer
    Meng, Fanliang
    Yi, Fangping
    Zheng, Sixun
    JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2008, 47 (03): : 450 - 462
  • [28] Methoxy poly(ethylene glycol)-block-poly(δ-valerolactone) copolymer micelles for formulation of hydrophobic drugs
    Lee, H
    Zeng, FQ
    Dunne, M
    Allen, C
    BIOMACROMOLECULES, 2005, 6 (06) : 3119 - 3128
  • [29] Synthesis and characterization of a poly(para-phenyleneethynylene)-block-poly(ethylene oxide) rod-coil block copolymer
    Francke, V
    Rader, HJ
    Geerts, Y
    Mullen, K
    MACROMOLECULAR RAPID COMMUNICATIONS, 1998, 19 (06) : 275 - 281
  • [30] Poly(ethylene glycol)-block-poly(butyl acrylate). II. Characterization and properties
    Lang, MD
    Zhang, G
    Chen, XF
    Feng, N
    Li, SH
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 70 (08) : 1427 - 1436