ANALYSIS OF NERVE AGENT DEGRADATION PRODUCTS USING CAPILLARY ION ELECTROPHORESIS

被引:46
|
作者
OEHRLE, SA [1 ]
BOSSLE, PC [1 ]
机构
[1] USA,EDGEWOOD RES,CTR DEV & ENGN,RES & TECHNOL DIRECTORATE,ABERDEEN PROVING GROUND,MD 21010
关键词
D O I
10.1016/0021-9673(94)01024-9
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A method has been developed for the analysis of nerve agent degradation products using capillary ion electrophoresis. Analysis of the primary degradation products isopropyl methylphosphonic acid, ethyl methylphosphonic acid, pinacolyl methylphosphonic acid and methylphosphonic acid was accomplished with run times of less than 5 min. Detection of low mg/l levels of degradation products in spiked water samples was possible. Little sample preparation was required for the analysis of the alkyl methylphosphonic acids.
引用
收藏
页码:247 / 252
页数:6
相关论文
共 50 条
  • [41] Determination of low parts-per-billion levels of chemical warfare agent degradation products in environmental samples using capillary electrophoresis.
    Nassar, AEF
    Lucas, SV
    Peterson, JC
    Myler, CA
    Hoffland, LD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U543 - U543
  • [42] Analysis of fission products using capillary electrophoresis with on-line radioactivity detection
    Klunder, GL
    Andrews, JE
    Grant, PM
    Andresen, BD
    Russo, RE
    ANALYTICAL CHEMISTRY, 1997, 69 (15) : 2988 - 2993
  • [43] Simultaneous separation of the enantiomers of cizolirtine and its degradation products by capillary electrophoresis
    Gómez-Gomar, A
    Ortega, E
    Calvet, C
    Mercé, R
    Frigola, J
    JOURNAL OF CHROMATOGRAPHY A, 2002, 950 (1-2) : 257 - 270
  • [44] Microchip capillary electrophoresis with electrochemical detection of thiol-containing degradation products of V-type nerve agents
    Wang, J
    Zima, J
    Lawrence, NS
    Chatrathi, MP
    Mulchandani, A
    Collins, GE
    ANALYTICAL CHEMISTRY, 2004, 76 (16) : 4721 - 4726
  • [45] ANALYSIS OF THE CONTRAST AGENT IOPAMIDOL IN SERUM BY CAPILLARY ELECTROPHORESIS
    SHIHABI, ZK
    ROCCO, MV
    HINSDALE, ME
    JOURNAL OF LIQUID CHROMATOGRAPHY, 1995, 18 (18-19): : 3825 - 3831
  • [47] ION-CHROMATOGRAPHIC SEPARATION OF CLOSELY-RELATED NERVE AGENT DEGRADATION PRODUCTS USING AN ORGANIC MODIFIER TO PROVIDE SELECTIVITY
    KINGERY, AF
    ALLEN, HE
    ANALYTICAL CHEMISTRY, 1994, 66 (01) : 155 - 159
  • [48] An optimized capillary electrophoresis method for the simultaneous analysis of biomass degradation products in ionic liquid containing samples
    Aid, Tiina
    Paist, Loore
    Lopp, Margus
    Kaljurand, Mihkel
    Vaher, Merike
    JOURNAL OF CHROMATOGRAPHY A, 2016, 1447 : 141 - 147
  • [49] PCR ANALYSIS USING CAPILLARY ELECTROPHORESIS
    KOEPF, SM
    ROSENBLUM, BB
    OAKS, F
    WENZ, M
    YAMANE, D
    SPURGEON, SL
    EFCAVITCH, B
    JOURNAL OF CELLULAR BIOCHEMISTRY, 1994, : 202 - 202
  • [50] USING CAPILLARY ELECTROPHORESIS FOR FAILURE ANALYSIS
    KELLY, RG
    SCULLY, HS
    STONER, GE
    MATERIALS PERFORMANCE, 1993, 32 (07) : 60 - 63