STRUCTURAL CHARACTERIZATION OF BIS(2,2'-BIPYRIDINE) [2-(2-PYRIDYL)PHENYL-C,N]RHODIUM(III) HEXAFLUOROPHOSPHATE - AN ANALOG OF A TRIS(2,2'-BIPYRIDINE) COMPLEX INCORPORATING A C,N-DONOR LIGAND

被引:22
|
作者
CONSTABLE, EC [1 ]
LEESE, TA [1 ]
TOCHER, DA [1 ]
机构
[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND
关键词
D O I
10.1016/S0277-5387(00)86581-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The preparation, spectroscopic and electrochemical properties of the cyclometallated complex [Rh(bipy)2(ppy)][PF6]2 are reported. The crystal and molecular structure of the complex are reported; the cation exhibits a six-fold disorder and closely resembles the [Rh(bipy)3]3+ cation. © 1990.
引用
收藏
页码:1613 / 1616
页数:4
相关论文
共 50 条
  • [21] Crystal structure of bis(2,2 '-bipyridine-kappa(2) N, N ')bis(thiocyanato-kappa N) manganese(II) 2,2 '-bipyridine monosolvate
    Suckert, Stefan
    Jess, Inke
    Naether, Christian
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M3 - +
  • [22] trans-diaquabis(2,2'-bipyridine-N,N')-ruthenium(II) bis(hexafluorophosphate)
    Weathers, NR
    Sadoski, RC
    Durham, B
    Cordes, AW
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1047 - 1049
  • [23] cis-Bis(2,2'-bipyridine-κ2 N,N')dichloridoiron(III) perchlorate
    Zhang, Zhi-Fang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M677 - U378
  • [24] Tris(2,2′-bipyridine-κ2N,N′)cadmium(II) bis(perchlorate) hemihydrate
    Zhang, Weiguang
    Jiang, Zhengjing
    Lu, Lude
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M7 - U185
  • [25] Tris(2,2'-bipyridine-kappa N-2,N')cobalt(II)bis(hexafluoridophosphate)
    Mentes, Ayfer
    Singh, Kuldip
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M58 - +
  • [26] Bis(2,2′-bipyridine-κ2N,N′)(nitrato-κO)copper(II) hexafluorophosphate
    Beobide, Garikoitz
    Castillo, Oscar
    Garcia-Couceiro, Urko
    Garcia-Teran, Juan P.
    Luque, Antonio
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1353 - M1355
  • [27] Electrochemistry of microparticles of tris(2,2′-bipyridine) ruthenium(II) hexafluorophosphate
    Ramaraj, R
    Kabbe, C
    Scholz, F
    ELECTROCHEMISTRY COMMUNICATIONS, 2000, 2 (03) : 190 - 194
  • [28] Mixed ligand Ru(II) complexes with 2,2′-bipyridine and 2-(2′-pyridyl)quinoxaline
    Garoufis, A
    Koutsodimou, A
    Katsaros, N
    Mitsopoulou, CA
    Hadjiliadis, N
    POLYHEDRON, 1999, 18 (3-4) : 361 - 369
  • [29] VANADIUM(II) REDUCTION OF TRIS(2,2'-BIPYRIDINE)COBALT(III) AND DISSOCIATION OF TRIS(2,2'-BIPYRIDINE)COBALT(II) PRODUCT
    DAVIES, R
    SYKES, AG
    GREEN, M
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (11): : 1171 - &
  • [30] LOW-TEMPERATURE PHOSPHORESCENCE AND ODMR IN A ZERO-FIELD OF 2,2'-BIPYRIDINE AND TRIS-(2,2'-BIPYRIDINE)RHODIUM(III)CHLORIDE
    KAMYSHNYI, AL
    ZAKHAROV, VN
    ASLANOV, LA
    SUISALU, AP
    AVARMAA, RA
    KOORDINATSIONNAYA KHIMIYA, 1989, 15 (04): : 548 - 555