STRUCTURAL CHARACTERIZATION OF BIS(2,2'-BIPYRIDINE) [2-(2-PYRIDYL)PHENYL-C,N]RHODIUM(III) HEXAFLUOROPHOSPHATE - AN ANALOG OF A TRIS(2,2'-BIPYRIDINE) COMPLEX INCORPORATING A C,N-DONOR LIGAND

被引:22
|
作者
CONSTABLE, EC [1 ]
LEESE, TA [1 ]
TOCHER, DA [1 ]
机构
[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND
关键词
D O I
10.1016/S0277-5387(00)86581-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The preparation, spectroscopic and electrochemical properties of the cyclometallated complex [Rh(bipy)2(ppy)][PF6]2 are reported. The crystal and molecular structure of the complex are reported; the cation exhibits a six-fold disorder and closely resembles the [Rh(bipy)3]3+ cation. © 1990.
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页码:1613 / 1616
页数:4
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